Synthesis and thermoelectric properties of Cs2Bi7.33Se12, A2Bi8Se13 (A = Rb, Cs), Ba4-xBi6+2/3xSe13, and Ba3±xPb3±xBi6Se15

被引：0

作者：

Iordanidis, L ^{[1
]}

Brazis, PW ^{[1
]}

Kannewurf, CR ^{[1
]}

Kanatzidis, MG ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, E Lansing, MI 48824 USA

来源：

THERMOELECTRIC MATERIALS 1998 - THE NEXT GENERATION MATERIALS FOR SMALL-SCALE REFRIGERATION AND POWER GENERATION APPLICATIONS | 1999年 / 545卷

关键词：

D O I：

暂无

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

We are continuing our synthetic investigations in the ternary A/Bi/Se systems and also expanded our interests into the quaternary A/M/Bi/Se (A = Rb, Cs, Sr and Ba; M = lanthanide or Pb) systems. We have synthesized several new ternary and quaternary bismuth selenides with band gaps <0.6eV such as CS2Bi7.33Se12, A(2)Bi(8)Se(13) (A = Rb, Cs), Ba4-xBi6+2/3xSe13, and Ba3+/-xPb3+/-xBi6Se15. The synthesis, crystal structures and charge transports properties of these new compounds are presented.

引用

页码：189 / 196

页数：8

共 50 条

[21] A novel framework type for inorganic clusters with cyanide ligands:: Crystal structures of Cs2Mn3[Re6Se8(CN)6]2•15 H2O and (H3O)2Co3[Re6Se8(CN)6]2•14.5 H2O
Naumov, NG
Virovets, AV
Sokolov, MN
Artemkina, SB
Fedorov, VE
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998, 37 (13-14) : 1943 - 1945
[22] New lanthanide selenophosphates.: Influence of flux composition on the distribution of [PSe4]3-/[P2Se6]4- units and the stabilization of the low-dimensional compounds A3REP2Se8, and A2(RE)P2Se7 (A = Rb, Cs; RE = Ce, Gd)
Chondroudis, K
Kanatzidis, MG
INORGANIC CHEMISTRY, 1998, 37 (15) : 3792 - 3797
[23] Ferrocenyl-passivated nanoclusters:: Synthesis of [CU20Se6(Se2fc)4(PR2R′)10] and [CU40Se12(Se2fc)8(PPh3)9]
Wallbank, AI
Borecki, A
Taylor, NJ
Corrigan, JF
ORGANOMETALLICS, 2005, 24 (05) : 788 - 790
[24] Unexpected ligand substitutions in the cluster core {Re6Se8}:: synthesis and structure of the novel cluster compound Cs11(H3O)[Re6Se4O4Cl6]3•4H2O
Yarovoi, SS
Mironov, YV
Solodovnikov, SF
Naumov, DY
Moroz, NK
Kozlova, SG
Simon, A
Fedorov, VE
CHEMICAL COMMUNICATIONS, 2005, (06) : 719 - 721
[25] POLYGERMANIUM COMPOUNDS .13. PERGERMA-ANALOGIES OF DIOXAN PH8GE4O2, PH8GE452, PH8GE4SE2 AND ETHYLENACETAL PH6GE3O2, PH6GE3S2, PH6GE3SE2
DRAGER, M
HABERLE, K
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 280 (02) : 183 - 196
[26] NEW TERNARY M2N-2MO6NX6N+2 CHALCOGENIDES (M = RB, CS X = S, SE) WITH CONDENSED MO6N CLUSTERS (N = 2, 3, 4, 5)
GOUGEON, P
PENA, O
POTEL, M
SERGENT, M
BRUSETTI, R
ANNALES DE CHIMIE-SCIENCE DES MATERIAUX, 1984, 9 (7-8): : 1079 - 1082
[27] Synthesis in molten alkali metal polythiophosphate fluxes. The new quaternary bismuth and antimony thiophosphates ABiP(2)S(7) (A=K, Rb), A(3)M(PS4)(2) (A=K, Rb, Cs; M=Sb, Bi), Cs3Bi2(PS4)(3), and Na0.16Bi1.28P2S6
McCarthy, T
Kanatzidis, MG
JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 236 (1-2) : 70 - 85
[28] Five New Chalcohalides, Ba3GaS4X (X = Cl, Br), Ba3MSe4Cl (M = Ga, In), and Ba7In2Se6F8: Syntheses, Crystal Structures, and Optical Properties
Feng, Kai
Yin, Wenlong
Lin, Zuohong
Yao, Jiyong
Wu, Yicheng
INORGANIC CHEMISTRY, 2013, 52 (19) : 11503 - 11508
[29] PHOTOELECTRIC PROPERTIES OF SEMICONDUCTING PHASES IN THE SYSTEMS A2ICVI-B2VC3VI (AI = LI, NA, K, RB, CS - BV = AS, SB, BI - CVI = S, SE, TE)
BAZAKUTSA, VA
GNIDASH, NI
PEREKRESTOV, VI
LAZAREV, VB
SALOV, AV
TRIPPEL, AF
INORGANIC MATERIALS, 1987, 23 (07) : 1020 - 1023
[30] Mixed valence effect of Se6+ and Zr4+ on structural, thermal, physical, and optical properties of B2O3-Bi2O3-SeO2-ZrO2 glasses
Thakur, Seema
Kaur, Anumeet
Singh, Lakhwant
OPTICAL MATERIALS, 2019, 96

← 1 2 3 4 5 →