Activated carbon prepared from Canadian oil sands coke by Co2 activation: II. Adsorption of metallic ions and organic constituents from oil sands tailings water

被引:6
|
作者
Karimi, Arash [1 ]
Thinon, Olivier [1 ]
Fournier, Joseph [2 ]
Hill, Josephine M. [1 ]
机构
[1] Univ Calgary, Dept Chem & Petr Engn, Calgary, AB T2N 1N4, Canada
[2] Suncor Oil Sands, Res Engn, Calgary, AB T2P 3E3, Canada
来源
关键词
oil sands coke; physical activation; post-oxidation; adsorption; tailings water; SURFACE-CHEMISTRY; PETROLEUM COKE; BASIC SITES; REMOVAL;
D O I
10.1002/cjce.21769
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Oil sands coke was activated with CO2 at 900 degrees C in a tubular fixed bed reactor. Samples activated in a CO2 stream with 50% air contained a significant number of functional groups. Some activated samples were post-oxidised in air at 350 degrees C to increase their surface functionality. Post-oxidation was necessary for the adsorption of ferric cations by the coke samples activated, except for the sample activated with 50% air. However, non-oxidised samples were also able to adsorb molybdate anions. Both organic and inorganic constituents of oil sands tailings water were successfully removed, but some inorganic species leached into water.
引用
收藏
页码:1500 / 1507
页数:8
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