Cerium Chloride Catalyzed Reduction Of Aromatic Esters To The Corresponding Alcohols With Sodium Borohydride In Water

被引：2
|
作者：
Zhu, Xun [1 ]
Wei, Yunyang [1 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China
来源：
ADVANCES IN CHEMICAL ENGINEERING, PTS 1-3 | 2012年 / 396-398卷
关键词：
Catalytic reduction; CeCl3 center dot 7H(2)O; NaBH4; Water as solvent; CARBOXYLIC-ACIDS; MILD; CONVENIENT; SOLVENT; SYSTEM; NABH4;
D O I：
10.4028/www.scientific.net/AMR.396-398.1936
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The aldehydes and ketones can be reduced readily by NaBH4 without any modification. NaBH4 can not reduce esters and their derivatives under ambient conditions, reflux and standing overn ight are necessary. However, the activity of NaBH4 can be enhanced by CeCl3 center dot 7H(2)O. In this article, a general, highly efficient and mild methodology for obtaining alcohol compounds by reduction of the corresponding esters with NaBH4 in the presence of a catalytic amount of CeCl3 center dot 7H(2)O in water is described.
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页码：1936 / 1939
页数：4
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