Co-Catalyzed Reductive Cyclization of Acrylate-Containing 1,6-Enynes

被引：5

作者：

Yang, Zhantao ^{[1
]}

Hou, Shenyin ^{[1
]}

Cheng, Yunfan ^{[1
]}

Sun, Li ^{[1
]}

Yang, Chun-Hua ^{[1
]}

机构：

[1] Anyang Normal Univ, Coll Chem & Chem Engn, Henan Key Lab New Optoelect Funct Mat, Anyang 455000, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2022年

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

TRANSITION; HYDROBORATION/CYCLIZATION; CYCLOISOMERIZATIONS; ALKENES; ALKYNES; IRON;

D O I：

10.1021/acs.joc.2c01345

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Co-catalyzed reductive cyclization of acrylatecontaining 1,6-enynes is reported, providing an approach to construct five-membered carbocyclic and heterocyclic scaffolds containing enol ethers and all-carbon quaternary carbons. This novel process enables an E/Z mixture of 1,6-enynes to react with good functional group tolerance and good isolated yields, in an operationally simple manner.

引用

页码：13339 / 13345

页数：7

共 50 条

[41] Cobalt-Catalyzed Ligand-Controlled Regioselective Hydroboration/Cyclization of 1,6-Enynes
Xi, Tuo
Lu, Zhan
ACS CATALYSIS, 2017, 7 (02): : 1181 - 1185
[42] Nickel-catalyzed arylative cyclization of 1,6-enynes: arylation of unactivated alkene moieties
Gao, Jian
Wei, Qi
Zhang, Zeqing
Su, Zhishan
Ming, Jialin
Zhang, Yongmin
ORGANIC CHEMISTRY FRONTIERS, 2024, 11 (16): : 4487 - 4495
[43] Mechanistic implications of nickel-catalyzed reductive coupling of aldehydes and chiral 1,6-enynes
Moslin, RM
Jamison, TF
ORGANIC LETTERS, 2006, 8 (03) : 455 - 458
[44] Rhodium-Catalyzed Asymmetric Cyclization/Addition Reactions of 1,6-Enynes and Oxa/Azabenzonorbornadienes
Zhou, Yongyun
Yu, Lu
Chen, Jingchao
Xu, Jianbin
He, Zhenxiu
Shen, Guoli
Fan, Baomin
ORGANIC LETTERS, 2018, 20 (05) : 1291 - 1294
[45] Palladium-Catalyzed Radical Cascade lododifluoromethylation/Cyclization of 1,6-Enynes with Ethyl Difluoroiodoacetate
Wang, Yu-Qi
He, Yu-Tao
Zhang, Lu-Lu
Wu, Xin-Xing
Liu, Xue-Yuan
Liang, Yong-Min
ORGANIC LETTERS, 2015, 17 (17) : 4280 - 4283
[46] Photoredox-catalyzed cascade [2+2+1] cyclization of 1,6-enynes with thiols
Meng, Zhe
Shi, Min
Wei, Yin
ORGANIC CHEMISTRY FRONTIERS, 2024, 11 (12) : 3442 - 3450
[47] Enantioselective cyclization/hydrosilylation of 1,6-enynes catalyzed by a cationic rhodium bis(phosphine) complex
Chakrapani, H
Liu, C
Widenhoefer, RA
ORGANIC LETTERS, 2003, 5 (02) : 157 - 159
[48] Copper-Catalyzed Sulfonyl Radical-Enabled Regioselective Cyclization of 1,6-Enynes
Zhang, Jun-Yao
Bao, Wen-Hui
Qin, Fu-Hua
Lei, Ke-Wei
Li, Qiang
Wei, Wen-Ting
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 8 (11) : 2050 - 2053
[49] Reductive Cyclization of 1,6-and 1,7-Enynes Catalyzed by Iron Complexes
Xi, Tuo
Chen, Xu
Zhang, Heyi
Lu, Zhan
SYNTHESIS-STUTTGART, 2016, 48 (17): : 2837 - 2844
[50] Missing cyclization pathways and new rearrangements unveiled in the gold(I) and platinum(II)-catalyzed cyclization of 1,6-enynes
Ferrer, Catalina
Raducan, Mihai
Nevado, Cristina
Claverie, Christelle K.
Echavarren, Antonio M.
TETRAHEDRON, 2007, 63 (27) : 6306 - 6316

← 1 2 3 4 5 →