Co-Catalyzed Reductive Cyclization of Acrylate-Containing 1,6-Enynes

被引：5

作者：

Yang, Zhantao ^{[1
]}

Hou, Shenyin ^{[1
]}

Cheng, Yunfan ^{[1
]}

Sun, Li ^{[1
]}

Yang, Chun-Hua ^{[1
]}

机构：

[1] Anyang Normal Univ, Coll Chem & Chem Engn, Henan Key Lab New Optoelect Funct Mat, Anyang 455000, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2022年

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

TRANSITION; HYDROBORATION/CYCLIZATION; CYCLOISOMERIZATIONS; ALKENES; ALKYNES; IRON;

D O I：

10.1021/acs.joc.2c01345

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Co-catalyzed reductive cyclization of acrylatecontaining 1,6-enynes is reported, providing an approach to construct five-membered carbocyclic and heterocyclic scaffolds containing enol ethers and all-carbon quaternary carbons. This novel process enables an E/Z mixture of 1,6-enynes to react with good functional group tolerance and good isolated yields, in an operationally simple manner.

引用

页码：13339 / 13345

页数：7

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