Magnetic properties of Fe-Co catalysts used for carbon nanofiber synthesis

被引:8
|
作者
Sorge, K. D. [1 ]
Klein, K. L. [2 ,3 ]
Melechko, A. V. [4 ]
Finkel, C. L. [1 ]
Malkina, O. [1 ]
Leventouri, Th. [1 ]
Fowlkes, J. D. [2 ,3 ]
Rack, P. D. [2 ,3 ]
Simpson, M. L. [2 ,3 ]
机构
[1] Florida Atlantic Univ, Dept Phys, Boca Raton, FL 33431 USA
[2] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA
[3] Univ Tennessee, Dept Mat Sci & Engn, Knoxville, TN 37996 USA
[4] Oak Ridge Natl Lab, Div Mat Sci & Technol, Oak Ridge, TN 37831 USA
关键词
D O I
10.1063/1.2960572
中图分类号
O59 [应用物理学];
学科分类号
摘要
The magnetic properties of Fe-Co alloys used as catalysts for vertically aligned carbon nanofiber growth are presented at several stages in the formation process: from thin films to dewetted islands to carbon-encapsulated particles. Electron microscopy shows their morphological properties as a function of the alloy ratio. The magnetic properties are investigated by superconducting quantum interference device magnetometry in a field range of vertical bar H vertical bar <= 20 kOe and temperatures between 2 and 330 K. Magnetization measurements illustrate a composition dependence of the magnetic properties. In addition, there is a significant amount of metal that is not incorporated in the resultant catalyst particles. This metal is superparamagnetic (SPM) and features of the magnetization curve shed light on the magnetic moment distribution of these SPM clusters. (c) 2008 American Institute of Physics.
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页数:7
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