Cobalt-catalyzed dimerization of α-olefins to give linear α-olefin products

被引：33
|
作者：
Broene, RD [1 ]
Brookhart, M
Lamanna, WM
Volpe, AF
机构：
[1] Bowdoin Coll, Dept Chem, Brunswick, ME 04011 USA
[2] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
[3] 3M Co, 3M Ctr, St Paul, MN 55144 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 49期
关键词：
D O I：
10.1021/ja056655n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[Cp*P(OMe) 3CoCH 2CH 3] + [BarF] -, generated by the addition of HBArF to Cp*P(OMe) 3Co(ethene), catalyzes the oligomerization of 1-hexene to give dimers and trimers. When a deficit of the acid is used, linear α-olefin dimers are produced at the expense of trimeric products: e.g., 1-butene, 1-hexene, and 1-octene give 1-octene, 1-dodecene, and 1-hexadecene, respectively. Copyright © 2005 American Chemical Society.
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页码：17194 / 17195
页数：2
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