FeCl3(Py)4, FeCl3[(NH2)2CO]6 and FeCl3[(NH2)2CS]6 as efficient catalysts for the efficient reduction of carbonyl compounds with NaBH4 under aprotic condition

被引：0
|
作者：
Haghgooie, Hossein [1 ]
Zeynizadeh, Behzad [1 ]
Shafaghi, Maryam [1 ]
机构：
[1] Urmia Univ, Dept Chem, Fac Sci, Orumiyeh 57159165, Iran
来源：
ASIAN JOURNAL OF CHEMISTRY | 2008年 / 20卷 / 08期
关键词：
carbonyl compounds; catalyst; iron(III) compounds; sodium borohydride;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
FeCl3(Py)(4), FeCl3[(NH2)(2)CO](6) and FeCl3[(NH2)(2)CS](6) are used as efficient catalysts for reduction of a variety of carbonyl compounds such as aldehydes, ketones, acyloins, alpha-diketones and conjugated carbonyl compounds with NaBH, under aprotic condition. The corresponding alcohols are obtained in high to excellent yields. Reduction reactions are performed in CH3CN at room temperature or reflux.
引用
收藏
页码：6033 / 6046
页数：14
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