Copper-catalyzed ortho-halogenation of protected anilines

被引：88
|
作者：
Urones, Beatriz [1 ]
Manu Martinez, Angel [1 ]
Rodriguez, Nuria [1 ]
Gomez Arrayas, Ramon [1 ]
Carretero, Juan C. [1 ]
机构：
[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 94期
关键词：
H BOND ACTIVATION; MOLECULAR-OXYGEN; PALLADIUM; FUNCTIONALIZATION; OXIDATION;
D O I：
10.1039/c3cc47174h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A practical Cu-catalyzed direct ortho-halogenation of anilines under aerobic conditions has been developed. The reaction shows typically excellent mono-substitution selectivity, high ortho-regiocontrol and large functional group tolerance.
引用
收藏
页码：11044 / 11046
页数：3
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