Preparation and spectroscopic properties of some new diaroylmethanatoboron difluoride derivatives

被引：20
|
作者：
Wang, Dun-Jia [1 ]
Xu, Ben-Po [1 ]
Wei, Xian-Hong [1 ]
Zheng, Jing [1 ]
机构：
[1] Hubei Normal Univ, Hubei Key Lab Pollutant & Reuse Technol, Coll Chem & Environm Engn, Huangshi 435002, Peoples R China
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2012年 / 140卷
关键词：
Diaroylmethanatoboron difluoride; Preparation; Diaroylmethanes; Spectroscopic properties; BORON DIFLUORIDE; CRYSTAL-STRUCTURE; LUMINESCENCE;
D O I：
10.1016/j.jfluchem.2012.04.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Five diaroylmethanatoboron difluoride derivatives were prepared from aryl methyl ketones via Claisen condensation with aromatic esters and followed by complexation with boron trifluoride etherate. Their structures and spectroscopic properties were studied by elemental analysis, IR, NMR, ESI-MS, UV and fluorescence spectroscopy. The results showed that these boron complexes had strong fluorescent peaks in the 400-500 nm range in chloroform and high quantum yields. The emission peaks for boron complexes containing naphthyl group exhibited considerable red shift as compared to those of containing phenyl group. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：49 / 53
页数：5
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