Synthesis of unsymmetrical carboxyphthalocyanines by palladium-catalyzed hydroxycarbonylation of iodo-substituted precursors

被引：18

作者：

de Carcer Garcia, Inigo Aguirre ^{[1
]}

Mert Sevim, Altug ^{[1
]}

de la Escosura, Andres ^{[1
]}

Torres, Tomas ^{[1
,2
]}

机构：

[1] Univ Autonoma Madrid, Dept Organ Chem, Canto Blanco 28049, Spain

[2] IMDEA Nanociencia, Madrid 28049, Spain

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2013年 / 11卷 / 14期

关键词：

SENSITIZED SOLAR-CELLS; ZINC PHTHALOCYANINES; CARBONYLATION; EFFICIENCY; HALIDES;

D O I：

10.1039/c3ob27468c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phthalocyanines (Pcs) containing a carboxylic acid functionality directly bound to the macrocycle have been synthesized, in one step and in good yields, from iodo-substituted Pc precursors. This methodology represents a convenient alternative to the commonly used method based on two consecutive oxidations of hydroxymethyl Pcs.

引用

页码：2237 / 2240

页数：4

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