Ferrocene-tagged N-heterocyclic carbene-Pd complex for Suzuki-Miyaura coupling

被引：7

作者：

Pore, Dattaprasad M. ^{[1
]}

Gaikwad, Dipak S. ^{[1
]}

Patil, Jayavant D. ^{[1
]}

机构：

[1] Shivaji Univ, Dept Chem, Kolhapur 416004, Maharashtra, India

来源：

MONATSHEFTE FUR CHEMIE | 2013年 / 144卷 / 09期

关键词：

Suzuki reaction; Boronic acid pinacol ester; N-heterocyclic carbene; Aerobic condition; MAIN-GROUP ELEMENTS; TRANSITION-METALS; ARYLBORONIC ACIDS; MULTIPLE BONDS; ARYL CHLORIDES; HECK REACTION; LIGANDS; HALIDES; CATALYST;

D O I：

10.1007/s00706-013-0970-2

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We demonstrate that the ferrocene-tagged N-heterocyclic carbene (NHC)-Pd(II) complex can act as an efficient heterogeneous catalyst for Suzuki-Miyaura cross-coupling in dimethylformamide (DMF)-water. This complex was found to be an active and efficient catalyst for coupling of aryl iodides, bromides, and even less reactive chlorides with boronic acids and pinacol ester of boronic acid.

引用

页码：1355 / 1361

页数：7

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