Molecular-Level Understanding of the Carbonisation of Polysaccharides

被引:34
|
作者
Shuttleworth, Peter S. [1 ]
Budarin, Vitaliy [1 ]
White, Robin J. [2 ]
Gun'ko, Vladimir M. [3 ]
Luque, Rafael [4 ]
Clark, James H. [1 ]
机构
[1] Univ York, Green Chem Ctr Excellence, York YO10 5DD, Yorks, England
[2] IASS Inst Adv Sustainabil Studies eV, D-14467 Potsdam, Germany
[3] Chuiko Inst Surface Chem, UA-03164 Kiev, Ukraine
[4] Univ Cordoba, Dept Quim Organ, Cordoba 14014, Spain
基金
英国工程与自然科学研究理事会;
关键词
carbon; green chemistry; nanotechnology; renewable resources; sustainable chemistry; HYDROTHERMAL CARBONIZATION; MESOPOROUS CARBON; POROUS MATERIALS; SURFACE-AREA; STARCH; ADSORPTION; PYROLYSIS; BIOMASS; WATER; ACTIVATION;
D O I
10.1002/chem.201300825
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Understanding of both the textural and functionality changes occurring during (mesoporous) polysaccharide carbonisation at the molecular level provides a deeper insight into the whole spectrum of material properties, from chemical activity to pore shape and surface energy, which is crucial for the successful application of carbonaceous materials in adsorption, catalysis and chromatography. Obtained information will help to identify the most appropriate applications of the carbonaceous material generated during torrefaction and different types of pyrolysis processes and therefore will be important for the development of cost- and energy-efficient zero-waste biorefineries. The presented approach is informative and semi-quantitative with the potential to be extended to the formation of other biomass-derived carbonaceous materials.
引用
收藏
页码:9351 / 9357
页数:7
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