Loading of Two Related Metal-Organic Frameworks (MOFs), [Cu2(bdc)2(dabco)] and [Cu2(ndc)2(dabco)], with Ferrocene

被引：24
|
作者：
Heck, Romain [1 ]
Shekhah, Osama [1 ]
Zybaylo, Olexandra [1 ]
Weidler, Peter G. [1 ]
Friedrich, Frank [1 ]
Maul, Robert [2 ,3 ]
Wenzel, Wolfgang [4 ]
Woell, Christof [1 ]
机构：
[1] Karlsruher Inst Technol, Inst Funkt Grenzflachen, D-76344 Eggenstein Leopoldshafen, Germany
[2] Karlsruher Inst Technol, Steinbuch Ctr Comp, D-76021 Karlsruhe, Germany
[3] Karlsruher Inst Technol, DFG Ctr Funct Nanostruct, D-76021 Karlsruhe, Germany
[4] Karlsruher Inst Technol, Inst Nanotechnol INT, D-76021 Karlsruhe, Germany
来源：
POLYMERS | 2011年 / 3卷 / 03期
关键词：
ferrocene; loading; MOFs;
D O I：
10.3390/polym3031565
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We have studied the loading of two related, similar porous metal-organic frameworks (MOFs) [Cu-2(bdc)(2)(dabco)] (1), and [Cu-2(ndc)(2)(dabco)] (2) with ferrocene by exposing bulk powder samples to the corresponding vapor. On the basis of powder X-ray diffraction data and molecular dynamics (MD) calculations we propose that each pore can store one ferrocene molecule. Despite the rather pronounced similarity of the two MOFs a quite different behavior is observed, for 1 loading with ferrocene leads to an anisotropic 1% contraction, whereas for 2 no deformation is observed. Mossbauer spectroscopy studies reveal that the Fe oxidation level remains unchanged during the process. Time dependent studies reveal that the diffusion constant governing the loading from the gas-phase for 1 is approximately three times larger than the value for 2.
引用
收藏
页码：1565 / 1574
页数：10
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