Direct phenol synthesis by selective oxidation of benzene with molecular oxygen on an interstitial-N/Re cluster/zeolite catalyst

被引：125

作者：

Bal, R

Tada, M

Sasaki, T

Iwasawa, Y ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

[2] Univ Tokyo, Dept Complex Sci & Engn, Grad Sch Frontier Sci, Kashiwa, Chiba 2778561, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 03期

关键词：

chemical vapor deposition; cluster compounds; heterogeneous catalysis; oxidation; zeolites;

D O I：

10.1002/anie.200502940

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Remarkable selectivity (88% in the steady-state reaction and 94% in the pulse reaction) is observed in the direct synthesis of phenol from benzene with molecular oxygen over a Re/zeolite catalyst prepared by chemical-vapor deposition. The novel interstitial-N/Re clusters are formed with NH3 and are essential for the activity in the selective oxidation reaction. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：448 / 452

页数：5

共 34 条

[31] Direct preparation of oximes and Schiff bases by oxidation of primary benzylic or allylic alcohols in the presence of primary amines using Mn(III) complex of polysalicylaldehyde as an efficient and selective heterogeneous catalyst by molecular oxygen
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Alireza Shakeri
Mohammad Mohammadi
Marzieh Tabefam
[J]. Journal of the Iranian Chemical Society, 2017, 14 : 1917 - 1933
[32] Direct preparation of oximes and Schiff bases by oxidation of primary benzylic or allylic alcohols in the presence of primary amines using Mn(III) complex of polysalicylaldehyde as an efficient and selective heterogeneous catalyst by molecular oxygen
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Shakeri, Alireza
Mohammadi, Mohammad
Tabefam, Marzieh
[J]. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2017, 14 (09) : 1917 - 1933
[33] Synthesis and Characterization of Oligomeric Ionic Liquid/Heteropoly Acid Composite as a New Heterogeneous Catalyst through Anion-Exchange Method for Selective Cyclohexane Oxidation with Molecular Oxygen under Solvent-Free Conditions
Sammah, Neda
Ghiaci, Mehran
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2017, 56 (38) : 10597 - 10604
[34] Synthesis, characterization and catalytic oxidation of cyclohexene with molecular oxygen over host (nanopores of zeolite-Y)/guest ([Ni([R]2-N2X2)]2+(R = H, CH3; X = NH, O, S) nanocatalyst
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[J]. JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (06) : 980 - 995

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