Oxygen/phosphorus co-doped porous carbon from cicada slough as high-performance electrode material for supercapacitors

被引:58
|
作者
Chen, Bingwei [1 ,2 ,3 ,4 ]
Wu, Wenzhuo [5 ]
Li, Chunyang [1 ,2 ]
Wang, Yanfang [1 ,2 ,3 ,4 ]
Zhang, Yi [1 ,2 ]
Fu, Lijun [1 ,2 ]
Zhu, Yusong [1 ,2 ]
Zhang, Lixin [3 ,4 ]
Wu, Yuping [1 ,2 ,3 ,4 ]
机构
[1] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Jiangsu, Peoples R China
[2] Nanjing Tech Univ, Sch Energy Sci & Engn, Nanjing 211816, Jiangsu, Peoples R China
[3] Fudan Univ, Dept Chem, NEML, Shanghai 200433, Peoples R China
[4] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China
[5] Guanghua Cambridge Int Sch, Shanghai 201315, Peoples R China
关键词
ACTIVATED CARBON; RICE HUSK; PHOSPHORUS; NITROGEN; BIOMASS; CAPACITANCE; COMPOSITES; GRAPHENE; FIBERS; SHELLS;
D O I
10.1038/s41598-019-41769-y
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Synthesizing high-performance electrode materials plays a vital role in fabricating advanced supercapacitors. Heteroatom doping has been proved to be effective in enhancing the electrochemical properties of carbon-based electrodes. Herein, we report an O, P co-doped porous carbon (PC) originated from waste biomaterials, cicada sloughs. The PC possesses meso-/microporous structure with a large specific surface area (1945 m(2).g(-1)) and a high O, P co-doping ratio of 18 wt%. These superior factors together enable it to deliver high specific capacitance (295 F.g(-1) in 6 M KOH and 291 F.g(-1) in 1 M H2SO4), good cycling stability (100% capacitance retention after 10000 cycles in 1 M H2SO4) and rate performance. Therefore, from the respects of environment friendliness and cost effectivity, obtaining heteroatom doped carbons from the nature might be better compared to pyrolyzing heteroatom-containing chemicals.
引用
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页数:8
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