Studies on the Hydrogenation of Acetonitrile over Fresh Mo2C/γ-Al2O3 Catalyst by In-situ IR Spectroscopy

被引：0

作者：

Zhang Jing ^{[1
]}

Wu Weicheng ^{[1
]}

Liu Chuang ^{[1
]}

Ding Xiaoguang ^{[2
]}

Chu Gang ^{[1
]}

Zhang Jianguo ^{[3
]}

机构：

[1] Liaoning Shihua Univ, Coll Chem Chem Engn & Environm Engn, Fushun 113001, Peoples R China

[2] Liaoning Shihua Univ, Sch Comp & Commun Engn, Fushun 113001, Peoples R China

[3] Univ Shanghai Sci & Technol, Sch Med Instrument & Food Engn, Shanghai 200093, Peoples R China

来源：

CHINA PETROLEUM PROCESSING & PETROCHEMICAL TECHNOLOGY | 2015年 / 17卷 / 03期

基金：

中国国家自然科学基金;

关键词：

fresh Mo2C/gamma-Al2O3 catalyst; hydrogenation; acetonitrile; in situ IR spectroscopy; GAS-PHASE HYDROGENATION; LIQUID-PHASE; NICKEL-CATALYSTS; NITRILES; ADSORPTION; PERFORMANCE; MECHANISM; CARBIDE; GROWTH; AMINES;

D O I：

暂无

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The adsorption of acetonitrile, the co-adsorption of acetonitrile with CO, and hydrogenation of acetonitrile on fresh Mo2C/gamma-Al2O3 catalyst were studied by in situ IR spectroscopy. It was found out that CH3CN exhibited strong interaction with the fresh Mo2C/gamma-Al2O3 catalyst and was adsorbed mainly on Mo delta+ sites of fresh Mo2C/gamma-Al2O3 catalyst. Moreover, CH3CN could affect the shifting of IR spectra for CO adsorption towards a lower wave number. The IR spectroscopic study on acetonitrile hydrogenation showed that CH3CN could be easily hydrogenated in the presence of H-2 on the Mo2C/gamma-Al2O3 catalyst. Furthermore, it was observed that CH3CN could be selectively hydrogenated to imines on fresh Mo2C/gamma-Al2O3 catalyst. Additionally, the active sites of fresh Mo2C/gamma-Al2O3 catalyst might be covered with coke during the hydrogenation reaction of acetonitrile. The treatment of catalyst with hydrogen at 673 K could not completely remove coke deposits on the surface of the Mo2C/gamma-Al2O3 catalyst.

引用

页码：61 / 66

页数：6

共 50 条

[21] Catalytic decomposition of hydrazine over α-Mo2C/γ-Al2O3 catalysts
Chen, XW
Zhang, T
Zheng, MY
Xia, LG
Li, T
Wu, WC
Wang, XD
Li, C
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (19) : 6040 - 6047
[22] An IR study on the surface passivation of Mo2C/Al2O3 catalyst with O2, H2O and CO2
Wu, WC
Wu, ZL
Liang, CH
Ying, PL
Feng, ZC
Li, C
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (24) : 5603 - 5608
[23] Sulfur effect on Mo2N/γ-Al2O3 catalyst studied by in situ FT-IR spectroscopy
Wu, ZL
Chu, YJ
Yang, SW
Wei, ZB
Li, C
Xin, Q
[J]. JOURNAL OF CATALYSIS, 2000, 194 (01) : 23 - 32
[24] The promotion of nickel to Mo2C/Al2O3 catalyst for the partial oxidation of methane to syngas
Zhu, QL
Zhang, B
Yang, J
Wang, JX
Zhao, J
Ji, SF
Wang, HQ
[J]. NEW JOURNAL OF CHEMISTRY, 2003, 27 (11) : 1633 - 1638
[25] BENZENE HYDROGENATION OVER A PD/AL2O3 CATALYST
VANNICE, MA
NEIKAM, WC
[J]. JOURNAL OF CATALYSIS, 1971, 23 (03) : 401 - &
[26] Selective hydrogenation of acetylene over Pd/β-Mo2C catalyst: Experimental and theoretical studies
Wu, Qinglei
Shen, Chenyang
Liu, Chang-jun
[J]. MOLECULAR CATALYSIS, 2024, 569
[27] Hydrodeoxygenation of acrylic acid using Mo2C/Al2O3
Rocha, Angela S.
Souza, Leandro A.
Oliveira, Ricardo R., Jr.
Rocha, Alexandre B.
da Silva, Victor Teixeira
[J]. APPLIED CATALYSIS A-GENERAL, 2017, 531 : 69 - 78
[28] In situ IR studies on the mechanism of methanol synthesis over an ultrafine Cu/ZnO/Al2O3 catalyst
Sun, Q
Liu, CW
Pan, W
Zhu, QM
Deng, JF
[J]. APPLIED CATALYSIS A-GENERAL, 1998, 171 (02) : 301 - 308
[29] In situ ATR-IR study of nitrite hydrogenation over Pd/Al2O3
Ebbesen, Sune D.
Mojet, Barbara L.
Lefferts, Leon
[J]. JOURNAL OF CATALYSIS, 2008, 256 (01) : 15 - 23
[30] The effect of secondary metal on Mo2C/Al2O3 catalyst for the partial oxidation of methane to syngas
Zhu, QL
Zhang, B
Zhao, J
Ji, SF
Yang, R
Wang, JX
Wang, HQ
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 213 (02) : 199 - 205

← 1 2 3 4 5 →