Dielectric properties of onion-like carbon and detonation nanodiamond/polydimethysiloxane composites

被引：7
|
作者：
Macutkevic, Jan [1 ]
Banys, Juras [2 ]
Moseenkov, Sergey [3 ]
Kuznetsov, Vladimir [3 ,4 ]
Nunn, Nicholas [5 ]
Shenderova, Olga [5 ]
机构：
[1] Ctr Phys Sci & Technol, LT-01108 Vilnius, Lithuania
[2] Vilnius State Univ, Fac Phys, Radiophys Dept, LT-10222 Vilnius, Lithuania
[3] RAS, Boreskov Inst Catalysis SB, Novosibirsk 630090, Russia
[4] Natl Tomsk State Univ, Radiophys Dept, Tomsk, Russia
[5] Int Technol Ctr, Raleigh, NC 27715 USA
来源：
POLYMER COMPOSITES | 2015年 / 36卷 / 11期
基金：
俄罗斯基础研究基金会;
关键词：
PERCOLATION; TRANSITION; FILLER;
D O I：
10.1002/pc.23119
中图分类号：
TB33 [复合材料];
学科分类号：
摘要：
Results of dielectric investigations of onion-like carbon (OLC) and detonation nanodiamond (DND)/polydimethysiloxane composites in wide frequency (20 Hz-3 THz) and temperatures (26-300 K) ranges are presented. The percolation threshold in OLC composites is 6.8 vol%. Electrical conduction in the OLC composites above the percolation threshold occurs mainly due to electron tunneling between OLC clusters and quasi-one-dimensional hopping inside the clusters. Hopping almost vanishes at frequencies above 100 GHz, where phonon contribution to the dielectric permittivity dominates. At low concentrations of nanocarbon particles (concentrations below the percolation threshold for OLC), the dielectric properties of the OLC and DND composites are similar. However, DNDs provide a noticeable improvement of the mechanical properties of the composites, in contrast with OLC. Therefore, a combination of the two nanomaterials in the composites could be beneficial. (c) 2014 Society of Plastics Engineer
引用
收藏
页码：2084 / 2092
页数：9
相关论文
共 50 条
  • [11] Fabrication of onion-like carbon from nanodiamond by annealing
    Qin Zou
    MingZhi Wang
    YanGuo Li
    YuCheng Zhao
    LiangHua Zou
    Science in China Series E: Technological Sciences, 2009, 52 : 3683 - 3689
  • [12] Transformation of onion-like carbon from nanodiamond by annealing
    Zou, Q.
    Li, Y. G.
    Lv, B.
    Wang, M. Z.
    Zou, L. H.
    Zhao, Y. C.
    INORGANIC MATERIALS, 2010, 46 (02) : 127 - 131
  • [13] Transformation of onion-like carbon from nanodiamond by annealing
    Q. Zou
    Y. G. Li
    B. Lv
    M. Z. Wang
    L. H. Zou
    Y. C. Zhao
    Inorganic Materials, 2010, 46 : 127 - 131
  • [14] Characterisation of onion-like carbon fabricated by annealing nanodiamond
    Zou, Q.
    Li, Y. G.
    Wang, M. Z.
    Zou, L. H.
    Zhao, Y. C.
    MATERIALS RESEARCH INNOVATIONS, 2010, 14 (04) : 285 - 288
  • [15] Graphitization and microstructure transformation of nanodiamond to onion-like carbon
    Qiao, ZJ
    Li, JJ
    Zhao, NQ
    Shi, CS
    Nash, P
    SCRIPTA MATERIALIA, 2006, 54 (02) : 225 - 229
  • [16] Fabrication of onion-like carbon from nanodiamond by annealing
    Zou Qin
    Wang MingZhi
    Li YanGuo
    Zhao YuCheng
    Zou LiangHua
    SCIENCE IN CHINA SERIES E-TECHNOLOGICAL SCIENCES, 2009, 52 (12): : 3683 - 3689
  • [17] Fabrication of onion-like carbon from nanodiamond by annealing
    ZOU Qin
    Science China Technological Sciences, 2009, 52 (12) : 3683 - 3689
  • [18] High dielectric permittivity of percolative composites based on onion-like carbon
    Macutkevic, J.
    Seliuta, D.
    Valusis, G.
    Banys, J.
    Kuznetsov, V.
    Moseenkov, S.
    Shenderova, O.
    APPLIED PHYSICS LETTERS, 2009, 95 (11)
  • [19] HRTEM and Raman characterisation of the onion-like carbon synthesised by annealing detonation nanodiamond at lower temperature and vacuum
    Zou, Q.
    Wang, M. Z.
    Li, Y. G.
    Lv, B.
    Zhao, Y. C.
    JOURNAL OF EXPERIMENTAL NANOSCIENCE, 2010, 5 (06) : 473 - 487
  • [20] Use of Onion-Like Carbon to Reinforce Carbon Composites
    Galiguzov, A.
    Malakho, A.
    Minchuk, S.
    Oktiabrskaia, L.
    Lepin, V
    EURASIAN CHEMICO-TECHNOLOGICAL JOURNAL, 2018, 20 (03) : 201 - 208
12345