A Simple and Efficient Copper(II) Complex as a Catalyst for N-Arylation of Imidazoles

被引：12
|
作者：
Jiao, Yanli [1 ]
Yan, Nannan [1 ]
Xie, Jianwei [1 ]
Ma, Xiaowei [1 ]
Liu, Ping [1 ]
Dai, Bin [1 ]
机构：
[1] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832003, Xinjiang, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2013年 / 31卷 / 02期
关键词：
pyrrolecarbaldiminato-Cu complexes; homogeneous catalyst; N-arylation; imidazoles; N-heterocycles; ARYL HALIDES; COUPLING REACTIONS; C-N; CONTAINING HETEROCYCLES; IMINE LIGANDS; AMINES; IODIDES; WATER; DERIVATIVES; AMIDATION;
D O I：
10.1002/cjoc.201201121
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four inexpensive and air-/moisture-stable pyrrolecarbaldiminato-Cu complexes 14 were synthesized and evaluated to be a novel class of catalysts for the N-arylation of imidazoles with aryl halides. A variety of aryl iodides, bromides and activated aryl chlorides underwent the coupling with imidazoles, promoted by the catalyst 4, in moderate to good yields without the protection by an inert gas.
引用
收藏
页码：267 / 270
页数：4
相关论文
共 50 条
  • [21] Ceria-supported copper nanoparticles: A highly efficient and recyclable catalyst for N-arylation of indole
    Amadine, Othmane
    Maati, Houda
    Abdelouhadi, Karima
    Fihri, Aziz
    El Kazzouli, Said
    Len, Christophe
    El Bouari, Abdeslam
    Solhy, Abderrahim
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 395 : 409 - 419
  • [22] An efficient, reusable copper-oxide/carbon-nanotube catalyst for N-arylation of imidazole
    Gopiraman, Mayakrishnan
    Babu, Sundaram Ganesh
    Khatri, Zeeshan
    Kai, Wei
    Kim, Yoong Ahm
    Endo, Morinobu
    Karvembu, Ramasamy
    Kim, Ick Soo
    [J]. CARBON, 2013, 62 : 135 - 148
  • [23] An inexpensive and efficient copper catalyst for N-arylation of amines, Amides and nitrogen-containing heterocycles
    Guo, Xun
    Rao, Honghua
    Fu, Hua
    Jiang, Yuyang
    Zhao, Yufen
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (15) : 2197 - 2202
  • [24] An efficient copper-catalyzed N-arylation of pyridazinones with a structurally well-defined copper complex
    Pu, YM
    Ku, YY
    Grieme, T
    Henry, R
    Bhatia, AV
    [J]. TETRAHEDRON LETTERS, 2006, 47 (02) : 149 - 153
  • [25] Efficient Iron/Copper Cocatalyzed N-Arylation of Arylamines with Bromoarenes
    Liu, Xiaoyan
    Zhang, Songlin
    [J]. SYNLETT, 2011, (08) : 1137 - 1142
  • [26] Copper-diamine-catalyzed N-arylation of pyrroles, pyrazoles, indazoles, imidazoles, and triazoles
    Antilla, JC
    Baskin, JM
    Barder, TE
    Buchwald, SL
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (17): : 5578 - 5587
  • [27] An efficient base-free N-arylation of imidazoles and amines with arylboronic acids using copper-exchanged fluorapatite
    Kantam, M. Lakshmi
    Venkanna, Gopaldasu T.
    Sridhar, Chidara
    Sreedhar, Bojja
    Choudary, Boyapati M.
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (25): : 9522 - 9524
  • [28] An efficient polymer-supported copper(II) catalyst for the N-arylation reaction of N(H)-heterocycles with aryl halides as well as arylboronic acids
    Islam, Manirul
    Mondal, Sanchita
    Mondal, Paramita
    Roy, Anupam Singha
    Tuhina, Kazi
    Salam, Noor
    Paul, Sumantra
    Hossain, Dildar
    Mobarok, Manir
    [J]. TRANSITION METAL CHEMISTRY, 2011, 36 (04) : 447 - 458
  • [29] An efficient polymer-supported copper(II) catalyst for the N-arylation reaction of N(H)-heterocycles with aryl halides as well as arylboronic acids
    Manirul Islam
    Sanchita Mondal
    Paramita Mondal
    Anupam Singha Roy
    Kazi Tuhina
    Noor Salam
    Sumantra Paul
    Dildar Hossain
    Manir Mobarok
    [J]. Transition Metal Chemistry, 2011, 36 : 447 - 458
  • [30] A new copper complex on graphene oxide: A heterogeneous catalyst for N-arylation and C-H activation
    Mittal, Ayushi
    Kumari, Shweta
    Parmanand
    Yadav, Deepak
    Sharma, Sunil K.
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2020, 34 (02)
12345