TCNQ-embedded heptacene and nonacene: synthesis, characterization and physical properties

被引：8

作者：

Ye, Qun ^{[1
]}

Chang, Jingjing ^{[1
]}

Huang, Kuo-Wei ^{[2
,3
]}

Dai, Gaole ^{[1
]}

Chi, Chunyan ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[2] King Abdullah Univ Sci & Technol KAUST, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia

[3] KAUST Catalysis Ctr, Thuwal 239556900, Saudi Arabia

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2013年 / 11卷 / 37期

关键词：

FIELD-EFFECT TRANSISTORS; ELECTROCHEMICAL PROPERTIES; HIGH-PERFORMANCE; DIIMIDE; ACENES; 11,11,12,12-TETRACYANO-9,10-ANTHRAQUINODIMETHANE; HETEROACENES; MOLECULES; TETRACENE; DESIGN;

D O I：

10.1039/c3ob40796a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Incorporation of 7,7,8,8-tetracyanoquinodimethane (TCNQ) moieties into the acene backbone has been successfully achieved and two heptacene-TCNQ derivatives and one nonacene-TCNQ derivative have been synthesized and well characterized. Two TCNQ moieties have been embedded into heptacene and nonacene backbones for the first time. All the three compounds have good stability and solubility due to the presence of TCNQ moieties. Single crystal analysis revealed a bent butterfly-like conformation of these molecules. Their charge transport properties have been characterized using organic field effect transistors (OFETs).

引用

页码：6285 / 6291

页数：7

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