N-N bond cleavage in N-nitrosoarylamines

被引：2

作者：

Evans, Louise A. ^{[1
]}

Petrovic, Marija ^{[2
]}

Antonijevic, Milan ^{[2
]}

Wiles, Charlotte ^{[1
]}

Watts, Paul ^{[1
]}

Wadhawan, Jay ^{[1
]}

机构：

[1] Univ Hull, Dept Phys Sci Chem, Kingston Upon Hull HU6 7RX, Yorks, England

[2] Univ Belgrade, Tech Fac Bor, Belgrade, Serbia

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 33期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/jp710473a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rupture of N-N bonds in three specific N-nitrosoarylamines (N,N'-dimethyl-N,N-dinitroso-para-phenylenediamine, Cupferron, and N-nitrosodiphenylamine) upon electrochemical oxidation in acetonitrile solution is investigated. In two cases, viz., Cupferron and N-nitrosodiphenylamine, self-inhibition via partial blocking of the electrode due to adsorption is observed. In the case of the bis(nitroso)arylamine, waveshape analysis using the Marcus theory of steady-state voltammetry at microelectrodes suggests that the oxidation involves the formation of a dication before N-N bond cleavage or a mechanism of the ECEC type.

引用

页码：12928 / 12935

页数：8

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