N-N bond cleavage in N-nitrosoarylamines

被引：2
|
作者：
Evans, Louise A. [1 ]
Petrovic, Marija [2 ]
Antonijevic, Milan [2 ]
Wiles, Charlotte [1 ]
Watts, Paul [1 ]
Wadhawan, Jay [1 ]
机构：
[1] Univ Hull, Dept Phys Sci Chem, Kingston Upon Hull HU6 7RX, Yorks, England
[2] Univ Belgrade, Tech Fac Bor, Belgrade, Serbia
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 33期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1021/jp710473a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The rupture of N-N bonds in three specific N-nitrosoarylamines (N,N'-dimethyl-N,N-dinitroso-para-phenylenediamine, Cupferron, and N-nitrosodiphenylamine) upon electrochemical oxidation in acetonitrile solution is investigated. In two cases, viz., Cupferron and N-nitrosodiphenylamine, self-inhibition via partial blocking of the electrode due to adsorption is observed. In the case of the bis(nitroso)arylamine, waveshape analysis using the Marcus theory of steady-state voltammetry at microelectrodes suggests that the oxidation involves the formation of a dication before N-N bond cleavage or a mechanism of the ECEC type.
引用
收藏
页码：12928 / 12935
页数：8
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