Flame retardant epoxy resin based on bisphenol A epoxy resin modified by phosphoric acid

被引：35

作者：

Jiao, Chuanmei ^{[1
]}

Zhuo, Jinlong ^{[1
]}

Chen, Xilei ^{[1
]}

Li, Shaoxiang ^{[1
]}

Wang, Huajin ^{[2
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Shandong, Peoples R China

[2] Marine Chem Res Inst, Qingdao 266071, Shandong, Peoples R China

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2013年 / 114卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Epoxy resin; Flame retardant; Phosphoric acid; HYPERBRANCHED POLYPHOSPHATE ESTER; THERMAL-DECOMPOSITION; FLAMMABILITY; DEGRADATION; SYSTEMS;

D O I：

10.1007/s10973-012-2867-4

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Flame retardant epoxy resin (FREP) were synthesized from phosphoric acid and bisphenol A epoxy resin (BAEP). The structure of the FREP was characterized using FTIR and P-31 NMR. Then, several FREP/BAEP mass ratios were used to obtain materials with different phosphorus contents. The properties of the thermosetting materials were evaluated by limiting oxygen index, UL 94, cone calorimeter test, and thermogravimetric analysis. The results showed that the heat release rates and smoke production rates decreased greatly, and char residue increased with the increasing of FREP. It indicates that good flame retardant properties are related to the formation of a protective phosphorus-rich char layer.

引用

页码：253 / 259

页数：7

共 50 条

[41] An efficient flame retardant for epoxy resin: Preparation and pyrolytic behaviour
Yang, Baoping
Li, Xiang
Wang, Lurong
Zhang, Yabin
Cui, Jinfeng
Guo, Junhong
Tian, Li
HIGH PERFORMANCE POLYMERS, 2019, 31 (9-10) : 1009 - 1019
[42] Thermal properties and microencapsulation of a phosphate flame retardant with a epoxy resin
Baek, KH
Lee, JY
Hong, SH
Kim, JH
POLYMER-KOREA, 2004, 28 (05) : 404 - 411
[43] An Effective Flame Retardant and Smoke Suppression Oligomer for Epoxy Resin
Lv, Qiang
Huang, Jian-Qian
Chen, Ming-Jun
Zhao, Jing
Tan, Yi
Chen, Li
Wang, Yu-Zhong
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (27) : 9397 - 9404
[44] α-Aminophosphonate Derivatives for Enhanced Flame Retardant Properties in Epoxy Resin
Stanfield, Melissa K.
Carrascal, Jeronimo
Henderson, Luke C.
Eyckens, Daniel J.
MATERIALS, 2021, 14 (12)
[45] Flame-retardant Mechanism of Magnesium Oxychloride in Epoxy Resin
秦麟卿
Journal of Wuhan University of Technology(Materials Science Edition), 2009, 24 (01) : 127 - 131
[46] Flame retardant epoxy resin toughened and strengthened by a reactive compatibilizer
Sun, Jinhao
Wang, Bingtao
Guo, Zhenghong
Fang, Zhengping
Li, Juan
POLYMER, 2022, 248
[47] Synthesis of eugenol-modified epoxy resin and application on wood flame retardant coating
Zhong, Jian
Huang, Yishuai
Chen, Yongtong
Li, Liping
Guo, Chuigen
INDUSTRIAL CROPS AND PRODUCTS, 2022, 183
[48] Flame retardancy and mechanical properties of epoxy resin with the phytic acid-derived flame retardant
Wang, Song
Meng, Lingchen
Chen, Qi
Li, Sanxi
Zhang, Ailing
JOURNAL OF APPLIED POLYMER SCIENCE, 2023, 140 (44)
[49] Highly efficient flame-retardant and transparent epoxy resin
Zhong, Liu
Zhao, Yu
Tang, Qiaolin
Zhang, Kaixin
Deng, Weihao
Zhang, Lewen
Wang, Rong
Chen, Jin
Deng, Jingjing
Liao, Wang
Wang, Qiwei
Chen, Mingjun
Liu, Zhiguo
POLYMERS FOR ADVANCED TECHNOLOGIES, 2021, 32 (08) : 2940 - 2952
[50] Synthesis of a Multielement Flame Retardant and Its Application in Epoxy Resin
Duan, Huajun
Wan, Chao
Zhang, Chenhao
Liu, Chentao
Zhao, Huijuan
Ma, Huiru
ACS APPLIED POLYMER MATERIALS, 2023, 5 (03) : 1775 - 1785

← 1 2 3 4 5 →