Phase behaviour, structural properties and intermolecular interactions of systems based on substituted thiacalix[4]arene and nonionic surfactants

被引:12
|
作者
Selivanova, Natalia [1 ]
Gubaidullin, Aidar [2 ]
Padnya, Pavel [3 ]
Stoikov, Ivan [3 ]
Galyametdinov, Yuriy [1 ]
机构
[1] Kazan Natl Res Technol Univ, Phys & Colloid Chem Dept, Kazan, Russia
[2] RAS, Arbuzov Inst Organ & Phys Chem, Lab Diffract Res Methods, FRC Kazan Sci Ctr, Kazan, Russia
[3] Kazan Fed Univ, Organ Chem Dept, Kazan, Russia
基金
俄罗斯科学基金会;
关键词
Lyotropic mesophase; surfactant; thiacalix[4]arene; macrocyclic ionic liquids; LIQUID-CRYSTALS; IONIC LIQUIDS;
D O I
10.1080/02678292.2018.1503351
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supramolecular organised materials were prepared from nonionic surfactants and the following macrocyclic ionic liquids: n-tert-butylthiacalix[4]arenes containing quaternary ammonium fragments with amino acid substituents. Tetraethylene glycol monododecyl ether and decadiethylene glycol monododecyl ether were used as nonionic surfactants. They form lamellar and hexagonal mesophases in aqueous media, respectively. Liquid crystal and structural properties of these systems were studied. Intermolecular interactions of system components leading to formation of lyomesophases were estimated. Molecular structure of thiacalixarene contributes to the formation of a hydrogen bonding with surfactants. This process, in turn, initiates formation of a denser packed hexagonal structure. [GRAPHICS] .
引用
收藏
页码:415 / 421
页数:7
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