Growth process of polymer aggregates formed by perfluorooctyltriethoxysilane. Time-resolved near-IR and two-dimensional near-IR correlation studies

被引：5
|
作者：
Izawa, K
Ogasawara, T
Masuda, H
Okabayashi, H
O'Connor, CJ
Noda, I
机构：
[1] Nagoya Inst Technol, Dept Appl Chem, Showa Ku, Nagoya, Aichi 4668555, Japan
[2] Fuji Silysia Chem Ltd, Nakatsugawa Tech Ctr, Gifu 5099132, Japan
[3] Tokai Tech Ctr Fdn, Meito Ku, Nagoya, Aichi 4650021, Japan
[4] Univ Auckland, Dept Chem, Auckland, New Zealand
[5] Procter & Gamble Co, W Chester, PA USA
来源：
COLLOID AND POLYMER SCIENCE | 2002年 / 280卷 / 04期
关键词：
polymer aggregates; perfluorooctyltricthoxysilane; time-resolved NIR; 2D NIR correlation;
D O I：
10.1007/s00396-001-0621-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The polymerization of 1H, 1H, 2H, 2H-perfluorooctyltriethoxysilane in ethanol, catalyzed by 0.5, 1.0 and 2.0 M HCl.H2O, has been examined using time-resolved near-IR (NIR) and 2D NIR correlation techniques. The time-resolved NIR results have demonstrated that the growth of polymeric aggregates prior to the phase separation proceeds in a two-step process, which depends upon the HCl concentration. Furthermore, it has been found that the 2D NIR correlation data provide direct information on the sequence of the intricate reaction steps and interaction of participating components through hydrogen bonding in the growth process.
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页码：380 / 388
页数：9
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