Isobaric Vapor-Liquid Equilibrium Data for the System of 1-Methyl-2-Ethylbenzene+1,2,4-Trimethylbenzene at 10 kPa

被引：3

作者：

Yang, Shengkai ^{[1
]}

Wang, Yujie ^{[1
]}

Wang, Xuejing ^{[1
]}

Zhu, Yong ^{[1
]}

Chen, Na ^{[1
]}

机构：

[1] Henan Inst Sci & Technol, Sch Chem & Chem Engn, Xinxiang 453003, Henan, Peoples R China

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2013年 / 58卷 / 02期

关键词：

EXPRESSION; MIXTURES; EQUATION; ENERGY;

D O I：

10.1021/je301122r

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Vapor liquid equilibrium (VLE) data of 1-methyl-2-ethylbenzene ( 1M2EB) + 1,2,4-trimethylbenzene (124TMB) at 10 kPa were measured by using a modified Rose Williams type recirculation still. The thermodynamic consistency of the VLE data was examined by the Herrington and Fredenslund methods. Experimental data were correlated by the Wilson, nonrandom two-liquid (NRTL), and universal quasichemical activity coefficient (UNIQUAC) models. All of the models were satisfactorily correlated with the VLE data. The result showed that the UNIQUAC model was slightly more suitable to correlate the experimental data and no azeotropic behavior was observed.

引用

页码：398 / 401

页数：4

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