Efficient, direct synthesis of dimethyl carbonate from CO2 using a solid, calcined zirconium phenylphosphonate phosphite catalyst

被引：19

作者：

Unnikrishnan, Pulikkeel ^{[1
,2
]}

Varhadi, Poonam ^{[1
]}

Srinivas, Darbha ^{[1
,2
]}

机构：

[1] CSIR Natl Chem Lab, Catalysis Div, Pune 411008, Maharashtra, India

[2] Acad Sci & Innovat Res, New Delhi, India

来源：

RSC ADVANCES | 2013年 / 3卷 / 46期

关键词：

PHOSPHONATE PHOSPHITE; REACTION-MECHANISM; METHANOL; DIOXIDE;

D O I：

10.1039/c3ra44368j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct synthesis of dimethyl carbonate (DMC) from CO2 and methanol with 100 mol% selectivity using a solid, reusable, hydrophobic, calcined zirconium phenylphosphonate phosphite catalyst is reported for the first time. DMC yield as high as 26 mmol g(-1) catalyst correlated with the concentration of acid and base sites is obtained.

引用

页码：23993 / 23996

页数：4

共 50 条

[31] Synthesis of dimethyl carbonate from CO2, methanol, and epoxides using Re (CO)5 Cl/K2 CO3 as catalyst system
Jiang Jia-li
Hua Rui-mao
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2007, 23 (03) : 374 - 376
[32] Synthesis of dimethyl carbonate from ethylene carbonate and methanol using TS-1 as solid base catalyst
Tatsumi, T
Watanabe, Y
Koyano, KA
CHEMICAL COMMUNICATIONS, 1996, (19) : 2281 - 2282
[33] Research progress of CeO2-based catalysts for direct synthesis of dimethyl carbonate from CO2 and methanol
Guo, Yongle
Yang, Zhe
Li, Guixian
Tian, Junying
Jingxi Huagong/Fine Chemicals, 2024, 41 (08): : 1637 - 1646
[34] Direct synthesis of dimethyl carbonate from CO2 and methanol over CeO2 catalysts of different morphologies
UNNIKRISHNAN P
SRINIVAS DARBHA
Journal of Chemical Sciences, 2016, 128 : 957 - 965
[35] Direct synthesis of dimethyl carbonate from CO2 and methanol over ZIF-67/CeO2
Hu Li-Hua
Wang Xiao
Hu Kai-Ran
Chen Chen
Xu Zhi-Hao
Xu Wei
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2023, 39 (07) : 1315 - 1324
[36] Direct synthesis of dimethyl carbonate from CO2 and methanol over CeO2 catalysts of different morphologies
Unnikrishnan, P.
Darbha, Srinivas
JOURNAL OF CHEMICAL SCIENCES, 2016, 128 (06) : 957 - 965
[37] Modeling of Chemical Equilibrium and Gas Phase Behavior for the Direct Synthesis of Dimethyl Carbonate from CO2 and Methanol
Bustamante, Felipe
Orrego, Andres F.
Villegas, Sebastian
Villa, Aida L.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (26) : 8945 - 8956
[38] Boosting Dimethyl Carbonate Production from CO2 and Methanol using Ceria-Ionic Liquid Catalyst
Asare-Bediako, Bernard Baffour
Li, Mi
Houston, Austin
Vilmercati, Paolo
Mannella, Norman
Labbe, Nicole
Abdoulmoumine, Nourredine
CHEMSUSCHEM, 2024, 17 (12)
[39] Synthesis of dimethyl carbonate from CO2 and methanol over CexZr1-xO2 solid solution
Li, Aixue
Zhao, Ning
Xiao, Fukui
Wang, Xinfeng
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
[40] Synthesis of dimethyl carbonate from methanol and CO2 under low pressure
Liu, Kai
Liu, Chun
RSC ADVANCES, 2021, 11 (57) : 35711 - 35717

← 1 2 3 4 5 →