PRODUCTION OF LACTIC ACID FROM GLYCEROL BY APPLYING AN ALKALINE HYDROTHERMAL PROCESS USING HOMOGENEOUS CATALYSTS AND HIGH GLYCEROL CONCENTRATION

被引：5

作者：

Rodrigues, A. K. O. ^{[1
]}

Maia, D. L. H. ^{[1
]}

Fernandes, F. A. N. ^{[1
]}

机构：

[1] Univ Fed Ceara, Dept Engn Quim, BR-60455760 Fortaleza, Ceara, Brazil

来源：

BRAZILIAN JOURNAL OF CHEMICAL ENGINEERING | 2015年 / 32卷 / 03期

关键词：

Glycerol; Lactic acid; Hydrothermal processing; Homogeneous catalyst; LACTOBACILLUS-HELVETICUS; PAPER SLUDGE; FERMENTATION; CONVERSION; HYDROGENOLYSIS; OPTIMIZATION; HYDROLYSIS; WASTES; WHEY;

D O I：

10.1590/0104-6632.20150323s00003356

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The production of lactic acid from glycerol by means of the alkaline hydrothermal process was evaluated using high concentrations of glycerol. The operating conditions that influence the hydrothermal process were studied. Temperature (250 - 280 degrees C), catalyst to glycerol molar ratio (0.05 to 0.15), and water to glycerol volumetric ratio (0.8 to 1.5) were evaluated, as well as the use of NaOH and KOH as catalysts. A concentration of lactic acid of 122 g/L was obtained at 260 degrees C, 0.04 NaOH to glycerol molar ratio, 1.0 water to glycerol volumetric ratio and 3 h of reaction using crude glycerol as raw material. The results showed higher lactic acid concentration and productivity than the fermentative process and the hydrothermal process carried out using low initial glycerol concentration.

引用

页码：749 / 755

页数：7

共 50 条

[41] Lactic acid fermentation is the main aerobic metabolic pathway in Enterococcus faecalis metabolizing a high concentration of glycerol
Doi, Yuki
APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2018, 102 (23) : 10183 - 10192
[42] Lactic acid fermentation is the main aerobic metabolic pathway in Enterococcus faecalis metabolizing a high concentration of glycerol
Yuki Doi
Applied Microbiology and Biotechnology, 2018, 102 : 10183 - 10192
[43] Potential lactic acid production from crude glycerol as the precursor of polylactic acid analog : literature review
Hastati, D. Y.
Hambali, E.
Syamsu, K.
Warsiki, E.
INTERNATIONAL CONFERENCE ON BIOMASS: TECHNOLOGY, APPLICATION, AND SUSTAINABLE DEVELOPMENT, 2016, 2017, 65
[44] Synthesis of Bio-Additives: Transesterification of Ethyl Acetate with Glycerol using Homogeneous or Heterogeneous Acid Catalysts
Meireles, Bruno A.
Pereira, Vera Lucia P.
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2013, 24 (01) : 17 - U337
[45] TRIACETIN PRODUCTION FROM GLYCEROL USING HETEROGENEOUS CATALYSTS PREPARED FROM PEAT CLAY
Yanti, Noor Ridha
Heryani, Hesty
Putra, Meilana Dharma
Nugroho, Agung
INTERNATIONAL JOURNAL OF TECHNOLOGY, 2019, 10 (05) : 970 - 978
[46] Cu catalysts supported on CaO/MgO for glycerol conversion to lactic acid in alkaline medium employing a continuous flow reaction system
Bruno, Arthur M.
Simoes, Thiago D. R.
Souza, Mariana M. V. M.
Manfro, Robinson L.
RSC ADVANCES, 2020, 10 (52) : 31123 - 31138
[47] Escherichia coli Strains Engineered for Homofermentative Production of D-Lactic Acid from Glycerol
Mazumdar, Suman
Clomburg, James M.
Gonzalez, Ramon
APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 2010, 76 (13) : 4327 - 4336
[48] Process optimization and kinetic analysis of malic acid production from crude glycerol using Aspergillus niger
Iyyappan, J.
Bharathiraja, B.
Baskar, G.
Kamalanaban, E.
BIORESOURCE TECHNOLOGY, 2019, 281 : 18 - 25
[49] Synthesis of Crystalline Poly(lactic acid) from Glycerol By-product via Hydrothermal Reaction and Stereoselective Polymerization
Hasegawa, Takashi
Kishida, Hisanori
Nomura, Nobuyoshi
Moriya, Takehiko
CHEMISTRY LETTERS, 2015, 44 (03) : 375 - 377
[50] Continuous Production of Lactic Acid from Glycerol over Bifunctional Catalysts under Base-Free Conditions Using a Liquid- Phase Flow Reactor
Kano, Erisa
Aihara, Takeshi
Ghampson, I. Tyrone
Nogami, Takeyuki
Miura, Hiroki
Shishido, Tetsuya
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2022, 10 (37) : 12072 - 12081

← 1 2 3 4 5 →