Wool-SO3H and nano-Fe3O4@wool as two green and natural-based renewable catalysts in one-pot isocyanide-based multicomponent reactions

被引:12
|
作者
Shaabani, Ahmad [1 ]
Hezarkhani, Zeinab [1 ]
Faroghi, Mohammad Tayeb [1 ]
机构
[1] Shahid Beheshti Univ, Fac Chem, Tehran, Iran
来源
MONATSHEFTE FUR CHEMIE | 2016年 / 147卷 / 11期
关键词
Heterogeneous catalysis; Natural wool; Solid acids; Nanostructures; Green chemistry; Multicomponent reactions; SOLID ACID CATALYSTS; COMPLEX WOOL-PD; ASYMMETRIC HYDRATION; PHASE SYNTHESIS; DERIVATIVES; SILICA; NANOCATALYSTS; POLYSTYRENE; SULFONATION; KERATIN;
D O I
10.1007/s00706-016-1717-7
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Natural wool sulfonic acid (wool-SO3H) and wool-supported Fe3O4 nanoparticles (nano-Fe3O4@wool) with highly loaded Fe3O4 nanoparticles were simply synthesized and characterized by flame atomic absorption spectroscopy, X-ray diffraction, thermogravimetric analysis, and scanning electron microscopy. The successful synthesis of 3,4-dihydroquinoxalin-2-amine, 1,6-dihydropyrazine-2,3-dicarbonitrile, (cyanophenylamino)acetamide, tetrahydro-1H-1,5-benzodiazepine-2-carboxamide, and 4,5,6,7-tetrahydro-1H-1,4-diazepine-5-carboxamide derivatives shows that wool-SO3H and Fe3O4@wool nanocomposite have high catalytic activity and can be repetitively used as two biodegradable catalysts.
引用
收藏
页码:1963 / 1973
页数:11
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