PROTON-CONDUCTING MEMBRANES BASED ON COPOLYMER COMPOSITES

被引:0
|
作者
Myachina, G. F. [1 ]
Ermakova, T. G. [1 ]
Kuznetsova, N. P. [1 ]
Volkova, L. I. [1 ]
Trofimov, B. A. [1 ]
Mognonov, D. M. [2 ]
机构
[1] Russian Acad Sci, AE Favorsky Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
[2] Russian Acad Sci, Baikal Inst Nat Management, Siberian Branch, Irkutsk, Russia
关键词
1-vinyl-1,2,4-triazole; fluoroalkylmethacrylates; copolymers; heteropolyacids; proton-conductive polymer membranes;
D O I
暂无
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Copolymers of 1-vinyl-1,2,4-triazole with methyl methacrylate and fluoroalkylmethacrylates have been modified with phosphorus- and silicon-molybdenum heteropolyacids as well as copolymer of ethylene glycol vinyl glycidyl ether with N-phenylmaleimide to furnish new composite materials. The elastic films obtained show proton conductivity of about 10(-3)-10(-1) S/cm (after doping with orthophosphoric acid). They are promising candidates for the design of proton-conductive membranes.
引用
收藏
页码:379 / +
页数:2
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