Matrix effects on hydrogen-bonded complexes trapped in low-temperature matrices

被引：26

作者：

Barnes, Austin J. ^{[1
]}

Mielke, Zofia ^{[2
]}

机构：

[1] Univ Salford, Mat & Phys Res Ctr, Salford M5 4WT, Lancs, England

[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2012年 / 1023卷

关键词：

Hydrogen-bonded complexes; Matrix effects; Matrix isolation; ISOLATION VIBRATIONAL SPECTROSCOPY; ISOLATION INFRARED-SPECTROSCOPY; SULFUR-DIOXIDE DIMER; MOLECULAR-COMPLEXES; NITROGEN MATRIX; PROTON-TRANSFER; ARGON MATRIX; ACID; AMMONIA; HALIDES;

D O I：

10.1016/j.molstruc.2012.05.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

There are several different possible matrix effects on hydrogen-bonded complexes trapped in low-temperature matrices: hydrogen-bonded complexes may be stabilised (compared with the gas phase) as a result of being trapped in a low-temperature matrix; metastable hydrogen-bonded complexes may be trapped in matrices; the matrix may influence the extent of proton transfer in a hydrogen-bonded complex; the matrix may influence the structure of a hydrogen-bonded complex. Each of these possible effects is examined in turn using selected examples from the literature as well as our own work. (c) 2012 Elsevier B.V. All rights reserved.

引用

页码：216 / 221

页数：6

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