Matrix effects on hydrogen-bonded complexes trapped in low-temperature matrices

被引：26
|
作者：
Barnes, Austin J. [1 ]
Mielke, Zofia [2 ]
机构：
[1] Univ Salford, Mat & Phys Res Ctr, Salford M5 4WT, Lancs, England
[2] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2012年 / 1023卷
关键词：
Hydrogen-bonded complexes; Matrix effects; Matrix isolation; ISOLATION VIBRATIONAL SPECTROSCOPY; ISOLATION INFRARED-SPECTROSCOPY; SULFUR-DIOXIDE DIMER; MOLECULAR-COMPLEXES; NITROGEN MATRIX; PROTON-TRANSFER; ARGON MATRIX; ACID; AMMONIA; HALIDES;
D O I：
10.1016/j.molstruc.2012.05.020
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
There are several different possible matrix effects on hydrogen-bonded complexes trapped in low-temperature matrices: hydrogen-bonded complexes may be stabilised (compared with the gas phase) as a result of being trapped in a low-temperature matrix; metastable hydrogen-bonded complexes may be trapped in matrices; the matrix may influence the extent of proton transfer in a hydrogen-bonded complex; the matrix may influence the structure of a hydrogen-bonded complex. Each of these possible effects is examined in turn using selected examples from the literature as well as our own work. (c) 2012 Elsevier B.V. All rights reserved.
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页码：216 / 221
页数：6
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