Effect of temperature on the solvation of 15-crown-5 ether in water-ethanol and water-propan-1-ol mixtures

被引：5

作者：

Jozwiak, Malgorzata ^{[1
]}

Madej-Kielbik, Longina ^{[1
]}

Piekarski, Henryk ^{[1
]}

机构：

[1] Univ Lodz, Dept Phys Chem, PL-90236 Lodz, Poland

来源：

THERMOCHIMICA ACTA | 2013年 / 568卷

关键词：

15-Crown-5; ether; Water-ethanol mixture; Water-propan-1-ol mixture; Enthalpy of solution; Preferential solvation; COSOLVENT BINARY-MIXTURES; KIRKWOOD-BUFF-INTEGRALS; PREFERENTIAL SOLVATION; MIXED-SOLVENTS; ORGANIC-SOLVENTS; CROWN-ETHERS; THERMOCHEMICAL BEHAVIOR; HYDROPHOBIC HYDRATION; 298.15; K; N-METHYLFORMAMIDE;

D O I：

10.1016/j.tca.2013.06.023

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The enthalpies of solution of 15-crown-5 (15C5) ether in water-ethanol and water-propan-1-ol mixtures have been measured at 293.15-308.15 K. The relative importance of the solvation mechanism appeared to depend on co-solvent properties. The effect of temperature on the solvation process of 15C5 in the mixtures of water with ethanol or propan-1-ol was discussed. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：122 / 129

页数：8

共 50 条

[31] Complex Formation of Crown Ethers with Cations in Water–Organic Solvent Mixtures. III. Thermodynamics of Interaction Between Na+ Ion with 15-Crown-5 Ether in Water–Acetonitrile Mixtures at 25°C
Małgorzata Jóźwiak
Journal of Solution Chemistry, 2002, 31 : 589 - 599
[32] Separation of ethanol–propan-1-ol–butan-1-ol–water azeotropic mixture
A. Yu. Sebyakin
A. K. Frolkova
Theoretical Foundations of Chemical Engineering, 2015, 49 : 750 - 755
[33] Effect of the Temperature on the Process of Preferential Solvation of 1,4-Dioxane, 12-Crown-4, 15-Crown-5 and 18-Crown-6 Ethers in the Mixture of N-Methylformamide with Water: Composition of the Solvation Shell of the Cyclic Ethers
Jozwiak, Malgorzata
Trzmielak, Monika A.
Wasiak, Michal
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2023, 24 (10)
[34] TEMPERATURE COEFFICIENT OF SOLUBILITY OF SOME GLYCYL PEPTIDES IN WATER-ETHANOL MIXTURES
CONIO, G
CURLETTO, L
PATRONE, E
JOURNAL OF BIOLOGICAL CHEMISTRY, 1973, 248 (15) : 5448 - 5450
[35] EFFECT OF ALKYLPYRIDINIUM IODIDES AND LITHIUM PERCHLORATE ON SOLUBILITY OF BENZOIC ACID IN WATER, ETHANOL, AND WATER-ETHANOL MIXTURES
SERGEEVA, VF
ESKARAEVA, L
JOURNAL OF GENERAL CHEMISTRY USSR, 1962, 32 (09): : 2910 - &
[36] Recognition of potassium ion in water by 15-crown-5 functionalized gold nanoparticles
Lin, SY
Liu, SW
Lin, CM
Chen, CH
ANALYTICAL CHEMISTRY, 2002, 74 (02) : 330 - 335
[37] Complex Formation of Crown Ethers with Cations in the Water–Organic Solvent Mixtures. Part VIII.1 Thermodynamic of Interactions of Na+ Ion with 15-Crown-5 and Benzo-15-Crown-5 Ethers in the Mixtures of Water with Hexamethylphosphortriamide at 298.15 K
Małgorzata Jóźwiak
Journal of Solution Chemistry, 2004, 33 : 1073 - 1084
[38] STABILITY OF COMPLEXES OF Ni(II) AND 18-CROWN-6 ETHER IN WATER-ETHANOL SOLVENTS
Usacheva, T. R.
Kuranova, N. N.
Kabirzoda, D. N.
Kryukova, O. V.
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2024, 67 (10): : 105 - 113
[39] The Effects of Proline Isomerization on the Solvation Behavior of Elastin-Like Polypeptides in Water-Ethanol Mixtures
Zhao, Yani
Kremer, Kurt
MACROMOLECULAR RAPID COMMUNICATIONS, 2022, 43 (12)
[40] Complex formation of crown ethers with cations in water-organic solvent mixtures.: III.: Thermodynamics of interaction between Na+ ion with 15-crown-5 ether in water-acetonitrile mixtures at 25°C
Józwiak, M
JOURNAL OF SOLUTION CHEMISTRY, 2002, 31 (07) : 589 - 599

← 1 2 3 4 5 →