Asymmetric Catalysis for the Synthesis of Spirocyclic Compounds

被引：260
|
作者：
Franz, Annaliese K. [1 ]
Hanhan, Nadine V. [1 ]
Ball-Jones, Nicolas R. [1 ]
机构：
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
来源：
ACS CATALYSIS | 2013年 / 3卷 / 04期
关键词：
spirooxindole; asymmetric; catalytic; spirocyclic; spirocenter; spiroketals; spirolactones; HIGHLY ENANTIOSELECTIVE SYNTHESIS; ORGANOCATALYTIC DOMINO REACTIONS; INTRAMOLECULAR HECK REACTIONS; QUATERNARY CARBON CENTERS; 3+2 ANNULATION; DIELS-ALDER; 1,3-DIPOLAR CYCLOADDITION; SEMIPINACOL REARRANGEMENT; STEREOSELECTIVE-SYNTHESIS; PALLADIUM(II) COMPLEXES;
D O I：
10.1021/cs300801y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Spirocycles provide an exciting platform to develop and understand the reactivity and selectivity for a wide variety of catalysts while affording diverse strategies to access molecules with important applications. This review features recent examples in which a spirocenter is formed within the key step of a catalytic asymmetric process, in either an intramolecular or intermolecular fashion. Examples highlight notable spirocyclization strategies and compare the reactivity and selectivity for different classes of chiral organocatalysts and organometallic catalysts.
引用
收藏
页码：540 / 553
页数：14
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