Alkali metal polyphosphides in low dimensions: Synthesis and structure of [(CH3)(4)N]2RbP7(NH3) and [(C2H5)(4)N]CS2P11

被引：39

作者：

Korber, N ^{[1
]}

vonSchnering, HG ^{[1
]}

机构：

[1] MAX PLANCK INST FESTKORPERFORSCH,D-70506 STUTTGART,GERMANY

来源：

CHEMISCHE BERICHTE | 1996年 / 129卷 / 02期

关键词：

polyphosphides; heptaphosphanortricyclane; undecaphosphatrishomocubane; ufosane;

D O I：

10.1002/cber.19961290208

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Partial exchange of the alkali metal ions for tetraalkylammonium cations of Rb3P7 and Cs3P11 in Liquid ammonia results in the formation of [(CH3)(4)N]2RbP7(NH3) (1) and [(C2H5)(4)N]Cs2P11 (2) The crystal structures reveal the existence of one-dimensional (1)(infinity)[RbP7](2-) chains in the former and two-dimensional (2)(infinity)[Cs2P11](-) layers in the latter compound. The nortricyclane cage in 1 is distorted by one-sided coordination to the Rb ions in a manner that can be related to the valence tautomerism of the free P-7(3-) anion.

引用

页码：155 / 159

页数：5

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