Facilitated transport separation of benzene and cyclohexane with poly(vinyl alcohol)-AgNO3 membranes

被引：41
|
作者：
Bryant, DL
Noble, RD
Koval, CA
机构：
[1] UNIV COLORADO,DEPT CHEM & BIOCHEM,BOULDER,CO 80309
[2] UNIV COLORADO,DEPT CHEM ENGN,BOULDER,CO 80309
来源：
JOURNAL OF MEMBRANE SCIENCE | 1997年 / 127卷 / 02期
基金：
美国国家科学基金会;
关键词：
facilitated transport; organic separations;
D O I：
10.1016/S0376-7388(96)00267-0
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Facilitated transport membranes of poly(vinyl alcohol) containing Ag(I) ions as the carrier were prepared and characterized using ultraviolet-visible spectroscopy (W-Vis), elemental analysis (ICP-AE), scanning electron microscopy (SEM), and SEM(EDXR). Transport experiments were performed using benzene/cyclohexane feed mixtures having volume ratios of 8/2 and 2/8 (v/v). Permeation rates for benzene ranged 0.5-5.5 kg mu m m(-2) h(-1) and benzene/cyclohexane selectivities ranged 51-84, Effects on membrane performance of Ag(I) content, counter ion used, hydration, and degree of cross-linking were investigated.
引用
收藏
页码：161 / 170
页数：10
相关论文
共 50 条
  • [31] Preparation of poly(acrylic acid)/poly(vinyl alcohol) membrane for the facilitated transport of CO2
    Matsuyama, H
    Teramoto, M
    Matsui, K
    Kitamura, Y
    JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 81 (04) : 936 - 942
  • [32] Crosslinked poly(vinyl alcohol) membranes
    Bolto, Brian
    Tran, Thuy
    Hoang, Manh
    Xie, Zongli
    PROGRESS IN POLYMER SCIENCE, 2009, 34 (09) : 969 - 981
  • [33] The Thermal-Electrical Properties of Polyvinyl Alcohol/AgNO3 Films
    Liang, Sen
    Yang, Jianfeng
    Zhang, Xiao
    Bai, Yu
    JOURNAL OF APPLIED POLYMER SCIENCE, 2011, 122 (02) : 813 - 818
  • [34] Characterization of sodium alginate and poly(vinyl alcohol) blend membranes in pervaporation separation
    Korea Research Inst of Chemical, Technology, Taejon, Korea, Republic of
    J Appl Polym Sci, 5 (949-959):
  • [35] Selective separation of some heavy metals by poly(vinyl alcohol)-grafted membranes
    El-Rehim, HAA
    Hegazy, ESA
    Ali, AM
    JOURNAL OF APPLIED POLYMER SCIENCE, 2000, 76 (02) : 125 - 132
  • [36] Characterization of sodium alginate and poly(vinyl alcohol) blend membranes in pervaporation separation
    Yeom, CK
    Lee, KH
    JOURNAL OF APPLIED POLYMER SCIENCE, 1998, 67 (05) : 949 - 959
  • [37] Miscibility enhancement of poly(vinyl chloride)/polystyrene blend: Application to membrane separation of benzene from benzene/cyclohexane mixture by pervaporation
    Aouak, Taieb
    Alghamdi, Abdulaziz Ali
    Alrashdi, Ahlam Abdulrahman
    Ouladsmane, Mohamed
    Alam, Mohammad Mezbaul
    AlOthman, Zeid
    Naushad, Mu
    SEPARATION SCIENCE AND TECHNOLOGY, 2016, 51 (14) : 2440 - 2454
  • [38] SEPARATION CHARACTERISTICS OF PERVAPORATION MEMBRANE SEPARATION PROCESSES USING MODIFIED POLY(VINYL ALCOHOL) MEMBRANES
    HUANG, RYM
    RHIM, JW
    POLYMER INTERNATIONAL, 1993, 30 (01) : 123 - 128
  • [39] Specialty polymeric membranes.: 13.: Separation of benzene/cyclohexane mixtures through poly(vinylidene chloride-co-vinyl chloride)-graft-poly(butyl methacrylate) membranes
    Yoshikawa, M
    Tsubouchi, K
    SEPARATION SCIENCE AND TECHNOLOGY, 2000, 35 (12) : 1863 - 1878
  • [40] Pervaporation Performance of Polydimethylsiloxane Membranes for Separation of Benzene/Cyclohexane Mixtures
    Chen, Jian
    Li, Jiding
    Lin, Yangzheng
    Chen, Cuixian
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 112 (04) : 2425 - 2433
12345