Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation

被引:3
|
作者
Li, Xi-Yong [2 ]
Sun, Ya-Min [2 ]
Yuan, Jin-Wei [1 ]
机构
[1] Henan Univ Technol, Sch Chem & Chem Engn, Zhengzhou 450001, Henan, Peoples R China
[2] Weihai Ocean Vocat Coll, Dept Marine Biol & Med, Weihai 264300, Peoples R China
关键词
2-arylsulfonyl quinolone; chloroquinoline; metal-free catalysis; sodium arylsulfinates; sulfonylation; SULFINIC ACID SALTS; QUINOLINE N-OXIDES; ONE-POT SYNTHESIS; MEDIATED SULFONYLATION; EFFICIENT SYNTHESIS; SULFUR-DIOXIDE; ARYL SULFONES; DERIVATIVES; MILD; HETEROCYCLES;
D O I
10.1515/znb-2018-0007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An efficient protocol for the synthesis of 2-arylsulfonyl quinolines has been developed via a metal-free catalyzed cross-coupling reaction of chloroquinoline with sodium arylsulfinates in moderate-to-good yields under microwave irradiation. The reactions proceed with a wide range of substrates with good functional group tolerance.
引用
收藏
页码:295 / 303
页数:9
相关论文
共 50 条
  • [11] Metal-Free Decarboxylative Allylation of Oxime Esters under Light Irradiation
    Geniller, Lilian
    Ben Kraim, Hiba
    Clot, Eric
    Taillefer, Marc
    Jaroschik, Florian
    Prieto, Alexis
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2024, 30 (43)
  • [12] Direct and metal-free arylsulfonylation of alkynes with sulfonylhydrazides for the construction of 3-sulfonated coumarins
    Wei, Wei
    Wen, Jiangwei
    Yang, Daoshan
    Guo, Mengyuan
    Wang, Yingying
    You, Jinmao
    Wang, Hua
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (04) : 768 - 771
  • [13] Ionic-Liquid-Catalyzed Approaches under Metal-Free Conditions
    Zhao, Yanfei
    Han, Buxing
    Liu, Zhimin
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2021, 54 (16) : 3172 - 3190
  • [14] Sodium Methoxide Catalyzed Depolymerization of Waste Polyethylene Terephthalate Under Microwave Irradiation
    Mohsin M.A.
    Alnaqbi M.A.
    Busheer R.M.
    Haik Y.
    [J]. Catalysis in Industry, 2018, 10 (1) : 41 - 48
  • [15] Metal-free C(sp3)-H oxidation of 2-methylquinolines with PIDA under microwave irradiation
    Jiang, Long
    Huang, Yingyi
    Yan, Yiyan
    Xie, Yuanyuan
    [J]. TETRAHEDRON LETTERS, 2016, 57 (37) : 4149 - 4151
  • [16] Metal-Free Catalyzed Regioselective Allylic Trifluoromethanesulfonylation of Aromatic Allylic Alcohols with Sodium Trifluoromethanesulfinate
    Liao, Jianhua
    Guo, Wei
    Zhang, Zhenming
    Tang, Xiaodong
    Wu, Wanqing
    Jiang, Huanfeng
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2016, 81 (03): : 1304 - 1309
  • [17] Effect of a novel metal-free green synthesis catalyst on the positive role of microwave irradiation in hydrogen production from the hydrolysis of sodium borohydride
    Ekinci, Arzu
    Sahin, Omer
    Baytar, Orhan
    [J]. PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, 2024, 187 : 644 - 651
  • [18] The synthesis and characterization of metal-free and metallophthalocyanine polymers by microwave irradiation containing diazadithia macrocyclic moieties
    Kaya, Elif Celenk
    Karadeniz, Huelya
    Kantekin, Halit
    [J]. DYES AND PIGMENTS, 2010, 85 (03) : 177 - 182
  • [19] α-Sulfur as a metal-free catalyst to activate peroxymonosulfate under visible light irradiation for decolorization
    Lin, Kun-Yi Andrew
    Zhang, Zhi-Yu
    [J]. RSC ADVANCES, 2016, 6 (18): : 15027 - 15034
  • [20] Metal-Free Epoxidation of Alkenes with Molecular Oxygen and Benzaldehyde under Visible Light Irradiation
    Tada, Norihiro
    Okubo, Hiroaki
    Miura, Tsuyoshi
    Itoh, Akichika
    [J]. SYNLETT, 2009, (18) : 3024 - 3026