Metal-free catalyzed arylsulfonylation of chloroquinoline with sodium arylsulfinates under microwave irradiation

被引:3
|
作者
Li, Xi-Yong [2 ]
Sun, Ya-Min [2 ]
Yuan, Jin-Wei [1 ]
机构
[1] Henan Univ Technol, Sch Chem & Chem Engn, Zhengzhou 450001, Henan, Peoples R China
[2] Weihai Ocean Vocat Coll, Dept Marine Biol & Med, Weihai 264300, Peoples R China
关键词
2-arylsulfonyl quinolone; chloroquinoline; metal-free catalysis; sodium arylsulfinates; sulfonylation; SULFINIC ACID SALTS; QUINOLINE N-OXIDES; ONE-POT SYNTHESIS; MEDIATED SULFONYLATION; EFFICIENT SYNTHESIS; SULFUR-DIOXIDE; ARYL SULFONES; DERIVATIVES; MILD; HETEROCYCLES;
D O I
10.1515/znb-2018-0007
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
An efficient protocol for the synthesis of 2-arylsulfonyl quinolines has been developed via a metal-free catalyzed cross-coupling reaction of chloroquinoline with sodium arylsulfinates in moderate-to-good yields under microwave irradiation. The reactions proceed with a wide range of substrates with good functional group tolerance.
引用
收藏
页码:295 / 303
页数:9
相关论文
共 50 条
  • [1] Iron-catalysed regioselective arylsulfonylation of quinoline N-oxides with sodium arylsulfinates under microwave irradiation
    Mai, Wenpeng
    Lv, Mingxiu
    Zhang, Xiaofeng
    Lu, Kui
    [J]. JOURNAL OF CHEMICAL RESEARCH, 2017, (12) : 705 - 708
  • [2] Metal-free TBAI-catalyzed arylsulfonylation of activated alkenes with sulfonylhydrazides
    Yu, Wubin
    Hu, Peizhu
    Fan, Yuanyuan
    Yu, Congyao
    Yan, Xinhuan
    Li, Xiaoqing
    Xu, Xiangsheng
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2015, 13 (11) : 3308 - 3313
  • [3] Solvent- and metal-free hydroboration of alkynes under microwave irradiation
    Gioia, Bruna
    Arnaud, Alexandre
    Radix, Sylvie
    Walchshofer, Nadia
    Doleans-Jordheim, Anne
    Rocheblave, Luc
    [J]. TETRAHEDRON LETTERS, 2020, 61 (11-12)
  • [4] Synthesis of Thioethers and Thioesters with Alkyl Arylsulfinates as the Sulfenylation Agent under Metal-Free Conditions
    Li, Yahui
    Zhu, Fengxiang
    Wang, Zechao
    Wu, Xiao-Feng
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2016, 11 (24) : 3503 - 3507
  • [5] Metal-free, retro-cycloaddition of fulleropyrrolidines in ionic liquids under microwave irradiation
    Guryanov, Ivan
    Lopez, Alejandro Montellano
    Carraro, Mauro
    Da Ros, Tatiana
    Scorrano, Gianfranco
    Maggini, Michele
    Prato, Maurizio
    Bonchio, Marcella
    [J]. CHEMICAL COMMUNICATIONS, 2009, (26) : 3940 - 3942
  • [6] Synthesis of soluble metallophthalocyanines from a metal-free phthalocyanine by microwave irradiation
    Liu, LC
    Lee, CC
    Hu, AT
    [J]. JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2001, 5 (11) : 806 - 807
  • [7] The synthesis, using microwave irradiation and characterization of novel, metal-free and metallophthalocyanines
    Acar, Irfan
    Kantekin, Halit
    Biyiklioglu, Zekeriya
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (02) : 151 - 155
  • [8] Metal-free ATRP with oligopyrene as a photocatalyst under LED irradiation
    Wu, Shufang
    Zhang, Yushu
    Li, Zhiquan
    Liu, Xiaoxuan
    Yagci, Yusuf
    [J]. EUROPEAN POLYMER JOURNAL, 2024, 206
  • [9] Neutral, metal-free hydration of alkynes using microwave irradiation in superheated water
    Vasudevan, A
    Verzal, MK
    [J]. SYNLETT, 2004, (04) : 631 - 634
  • [10] Fast Transition Metal-Free Synthesis of Functionalized Oxindoles and Dihydroquinoline-2-ones Under Microwave Irradiation
    Couto, Julia L.
    Hornink, Milene M.
    Nascimento, Vinicius R.
    Andrade, Leandro H.
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 2022 (44)