Varieties of crystalline architecture by using hydrogen bonding in biimidazolate metal complex systems .2. One-dimensional linear chains

被引：3
|
作者：
Tadokoro, M
Isobe, K
Nakasuji, K
机构：
[1] OSAKA CITY UNIV,FAC SCI,DEPT MAT SCI,SUMIYOSHI KU,OSAKA 558,JAPAN
[2] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1996年 / 278卷
关键词：
D O I：
10.1080/10587259608033674
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
We observed lower shifted v(NH) bands and higher shifted 2 gamma(NH) overtone vibrations in [Cu(Hbim)(2)](n) (1) (Hbim(-) = mono deprotonated 2,2'-biimidazolate) in FT-IR spectroscopy. This observation demonstrated that complex 1 forms a hydrogen-bonding polymer with intermolecular NH-N hydrogen bonds between Hbim(-) ligands to give a one-dimensional linear structure.
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页码：209 / 212
页数：4
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