Organic functionalization of carbon nanotubes

被引:1050
|
作者
Georgakilas, V
Kordatos, K
Prato, M
Guldi, DM
Holzinger, M
Hirsch, A
机构
[1] Univ Trieste, Dipartimento Sci Farmaceut, I-34127 Trieste, Italy
[2] Univ Notre Dame, Radiat Lab, Notre Dame, IN 46556 USA
[3] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany
关键词
D O I
10.1021/ja016954m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A very general and versatile method for functionalizing different types of carbon nanotubes is described, using the 1,3-dipolar cycloaddition of azomethine ylides. Approximately one organic group per 100 carbon atoms of the nanotube is introduced, to yield remakably soluble bundles of nanotubes, as seen in transmission electron micrographs. The solubilization of the nanotubes generates a novel, interesting class of materials, which combines the properties of the nanotubes and the organic moiety, thus offering new opportunities for applications in materials science, including the preparation of nanocomposites. Copyright © 2002 American Chemical Society.
引用
收藏
页码:760 / 761
页数:2
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