Partial ionization cross-sections of H2O molecule by 10-25 keV electron ionization

The relative ionic fractions and the precursor-specific relative partial ionization cross-sections for the fragment ions formed in direct- and dissociative ionization of H2O molecule have been measured for the first time at 10-25 keV electron energies using the multiple ion coincidence imaging technique. We have identified six ions (H2O+, OH+, H+, O+, O2+ and H-2(+)) from the ionization of H2O molecule and have found that the relative ionic fractions for these fragments are almost invariant of impact energy. From multiple-ion coincidence spectra, we have identified three distinct fragmentation channels: namely, H+ + OH+, H+ + O+ + H and H+ + H+ + O resulting from dissociation of H2O2+ and two channels: H+ + O2+ + H and H+ + H+ + O+ resulting from the dissociation of H2O3+. From the analysis, we have estimated that about 94.4% of 'single ionization', 5.3% of 'double ionization' and 0.3% of 'triple ionization' of the parent molecule contribute to the total ion yield. It is further noted that the non-dominant fragment ions O2+ and H-2(+) possess appreciably larger relative ionic fractions than those obtained at lower impact energies. (c) 2013 Elsevier B.V. All rights reserved.