We consider linear arrays of cells of volume V-c populated by monodisperse rods of size sigma V-c, sigma = 1,2, ... , subject to hardcore exclusion interaction. Each rod experiences a position-dependent external potential. In one application we also examine effects of contact forces between rods. We employ two distinct methods of exact analysis with complementary strengths and different limits of spatial resolution to calculate profiles of pressure and density on mesoscopic and microscopic length scales at thermal equilibrium. One method uses density functionals and the other statistically interacting vacancy particles. The applications worked out include gravity, power-law traps, and hard walls. We identify oscillations in the profiles on a microscopic length scale and show how they are systematically averaged out on a well-defined mesoscopic length scale to establish full consistency between the two approaches. The continuum limit, realized as V-c -> 0, sigma -> infinity at nonzero and finite sigma V-c, connects our highest-resolution results with known exact results for monodisperse rods in a continuum. We also compare the pressure profiles obtained from density functionals with the average microscopic pressure profiles derived from the pair distribution function.
机构:
Curtin Univ, Dept Chem, Nanochem Res Inst, Perth, WA 6845, AustraliaCurtin Univ, Dept Chem, Nanochem Res Inst, Perth, WA 6845, Australia
Jia, Guohua
Xu, Shiqing
论文数: 0引用数: 0
h-index: 0
机构:
China Jiliang Univ, Coll Mat Sci & Engn, Hangzhou 310018, Zhejiang, Peoples R ChinaCurtin Univ, Dept Chem, Nanochem Res Inst, Perth, WA 6845, Australia
Xu, Shiqing
Wang, Aixiang
论文数: 0引用数: 0
h-index: 0
机构:
Linyi Univ, Sch Chem & Chem Engn, Linyi 276005, Peoples R ChinaCurtin Univ, Dept Chem, Nanochem Res Inst, Perth, WA 6845, Australia