High electrical conductivity and breakdown current density of individual monolayer Ti3C2Tx MXene flakes

被引:117
|
作者
Lipatov, Alexey [1 ]
Goad, Adam [2 ,3 ]
Loes, Michael J. [1 ]
Vorobeva, Nataliia S. [1 ]
Abourahma, Jehad [1 ]
Gogotsi, Yury [2 ,3 ]
Sinitskii, Alexander [1 ,4 ]
机构
[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA
[2] Drexel Univ, AJ Drexel Nanomat Inst, Philadelphia, PA 19104 USA
[3] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[4] Univ Nebraska, Nebraska Ctr Mat & Nanosci, Lincoln, NE 68588 USA
基金
美国国家科学基金会;
关键词
CURRENT-CARRYING CAPACITY; DEVICES; RISE;
D O I
10.1016/j.matt.2021.01.021
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
As the scaling down of integrated circuits continues, there is a growing interest in electrically conductive materials with high current-carrying capacity for next-generation on-chip interconnects. Here, we report very high breakdown current density in Ti3C2Tx MXene, an emerging two-dimensional material. We performed electrical measurements of individual high-quality monolayer Ti3C2Tx flakes, which were prepared by an improved synthesis method, and found that they exhibit electrical conductivities of up to 11,000 S cm(-1) and field-effect electron mobilities of up to 6 cm(2) V-1 s(-1), both representing the best values reported for Ti3C2Tx flakes so far. All flakes exhibited very similar breakdown current densities of about 1.2 x 10(8) A cm(2), which are comparable with the best two-dimensional materials, including graphene, The remarkable combination of high electrical conductivity and high current-carrying capacity makes Ti3C2Tx promising for nanometer-thin interconnects and warrants investigation of breakdown current densities of other materials from the large MXene family.
引用
收藏
页码:1413 / 1427
页数:15
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