Charge-Transfer Complexes Studied by Dynamic Force Spectroscopy

被引：3

作者：

Gomez-Casado, Alberto ^{[1
]}

Gonzalez-Campo, Arantzazu ^{[1
]}

Zhang, Yiheng ^{[2
]}

Zhang, Xi ^{[2
]}

Jonkheijm, Pascal ^{[1
]}

Huskens, Jurriaan ^{[1
]}

机构：

[1] Univ Twente, Mol Nanofabricat Grp, MESA Inst Nanotechnol, NL-7500 AE Enschede, Netherlands

[2] Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China

来源：

POLYMERS | 2013年 / 5卷 / 01期

关键词：

charge-transfer complex; dynamic force spectroscopy; methyl viologen; naphthol; pyrene; kinetics; MULTIPLE-BOND RUPTURES; ELECTRON-TRANSFER; PYRENE; AFM; METHYLVIOLOGEN; CALIBRATION; MICROSCOPY; RECEPTOR;

D O I：

10.3390/polym5010269

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In this paper, the strength and kinetics of two charge-transfer complexes, naphthol-methylviologen and pyrene-methylviologen, are studied using dynamic force spectroscopy. The dissociation rates indicate an enhanced stability of the pyrene-methylviologen complex, which agrees with its higher thermodynamic stability compared to naphthol-methylviologen complex.

引用

页码：269 / 283

页数：15

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