Photocatalytic degradation of an anionic dye in aqueous solution by visible light responsive zinc oxide-termite hill composite

被引:15
|
作者
Yusuff, Adeyinka S. [1 ]
Bello, Kazeem A. [2 ]
Azeez, Temitayo M. [2 ]
机构
[1] Afe Babalola Univ, Coll Engn, Dept Chem & Petr Engn, Lab Chem React Engn & Catalysis, Ado Ekiti, Nigeria
[2] Afe Babalola Univ, Coll Engn, Dept Mech & Mechatron Engn, Lab Mat Sci & Renewable Energy, Ado Ekiti, Nigeria
关键词
Photocatalysis; Acid blue 113; Photodegradation; Kinetics; Mineralization; METHYLENE-BLUE; WASTE-WATER; TIO2; DECOLORIZATION; NANOCOMPOSITE; PHENOL;
D O I
10.1007/s11144-020-01839-z
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present study investigated the photocatalytic potential of zinc oxide-termite hill composite (ZnO-TH) for anionic dye (acid blue 113, AB113) degradation in aqueous solution. The composite photocatalyst was prepared using the sol-gel method. The material properties were characterized using techniques such as gas sorption, scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and titration for the determination of the surface charge. The photocatalytic conditions effect on AB113 dye degradation efficiency was examined at a fixed irradiation time of 60 min. It was identified that the optimum values of the initial dye concentration, aqueous solution pH and photocatalyst loading were 25 mg/L, 3.0 and 1.2 g/L, respectively. At these optimum conditions, the maximum decolorization efficiency was found to be 92.21%. AB113 dye was almost completely mineralized after 60 min of visible light irradiation in the presence of the ZnO-TH composite. The photocatalyst showed good stability after being reused for five times.
引用
收藏
页码:537 / 554
页数:18
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