Synthesis and characterization of a new organically templated open-framework beryllium phosphite with 3, 4-connected networks

被引：3

作者：

Wang, Guo-Ming ^{[1
]}

Zhang, Xiao ^{[1
]}

Li, Jin-Hua ^{[1
]}

Wang, Pei ^{[1
]}

Wang, Zong-Hua ^{[1
]}

Wang, Ying-Xia ^{[2
]}

Lin, Jian-Hua ^{[2
]}

机构：

[1] Qingdao Univ, Teachers Coll, Coll Chem & Environm, Shandong 266071, Peoples R China

[2] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

来源：

SOLID STATE SCIENCES | 2014年 / 27卷

基金：

中国国家自然科学基金;

关键词：

Beryllium phosphite; Hydrothermal synthesis; Crystal structure; Open-framework; 12-Ring channel; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; STRUCTURAL CHARACTERIZATION; NICKEL(II) PHOSPHATE; ZINC PHOSPHATE; ZEOLITES;

D O I：

10.1016/j.solidstatesciences.2013.11.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Employing diethylenetriamine (=dien) as a structure-directing agent, a new open-framework beryllium phosphite H(2)dien center dot Be-3(HPO3)(4) (1), has been synthesized hydrothermally and structurally characterized by single crystal X-ray diffraction. The structure of 1 features a (3, 4)-connected framework with 8- and 12-ring channels, which is constructed from strictly alternating BeO4 tetrahedra and HPO32- pseudo-pyramids. The 3-D framework possesses a pcu topology when the heptameric [Be-3(HPO3)(4)] clusters are regarded as 6-connected secondary building units. Crystal data: 1, monoclinic, C2/c (no. 15), a = 8.7350(3) angstrom, b = 15.1704(6) angstrom, c = 13.0851(4) angstrom, beta = 101.223(5)degrees, V = 1700.79(10) angstrom(3), Z = 4, R-1 = 0.0625, wR(2) = 0.1692. (C) 2013 Elsevier Masson SAS. All rights reserved.

引用

页码：55 / 59

页数：5

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