How Mossbauer spectroscopy can improve Li-ion batteries

被引：18

作者：

Lippens, Pierre-Emmanuel ^{[1
]}

El Khalifi, Mohammed ^{[1
]}

Chamas, Mohamad ^{[1
]}

Perea, Alexis ^{[1
]}

Sougrati, Moulay-Tahar ^{[1
]}

Ionica-Bousquet, Costana ^{[1
]}

Aldon, Laurent ^{[1
]}

Olivier-Fourcade, Josette ^{[1
]}

Jumas, Jean-Claude ^{[1
]}

机构：

[1] Univ Montpellier 2, Inst Charles Gerhardt, Equipe Agregats Interface & Mat Energie, CNRS,UMR 5253, F-34095 Montpellier 5, France

来源：

HYPERFINE INTERACTIONS | 2012年 / 206卷 / 1-3期

关键词：

Mossbauer spectroscopy; In situ; Operando; Li-ion batteries; Electrode materials; LiFePO4; Tin; Intermetallics; NEGATIVE ELECTRODE MATERIALS; X-RAY-DIFFRACTION; TIN-COBALT-CARBON; SN-119; MOSSBAUER; IN-SITU; ELECTROCHEMICAL PROPERTIES; INSERTION MECHANISMS; LITHIUM INSERTION; ALLOY ANODES; LIFEPO4;

D O I：

10.1007/s10751-011-0418-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

In the domain of Li-ion batteries, Mossbauer spectroscopy is mainly used for the characterization of electrode materials and the analysis of electrochemical reactions. Depending on the properties under investigation, different approaches are often considered, which are based on ex situ, in situ and operando measurements. The specific electrochemical cells and sample preparations used for such measurements are described in this paper. Applications to selected examples of cathode and anode materials are presented in order to show how Mossbauer spectroscopy, when associated with other techniques, provides essential information to understand the mechanisms and improves the performances of Li-ion batteries.

引用

页码：35 / 46

页数：12

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