Efficient Tuning Nonlinear Optical Properties: Synthesis and Characterization of a Series of Novel Poly(aryleneethynylene)s Co-Containing BODIPY

被引：67
|
作者：
Zhu, Mei [1 ,2 ]
Jiang, Li [1 ]
Yuan, Mingjian [1 ,2 ]
Liu, Xiaofeng [1 ,2 ]
Ouyang, Canbin [1 ,2 ]
Zheng, Haiyan [1 ,2 ]
Yin, Xiaodong [1 ,2 ]
Zuo, Zicheng [1 ,2 ]
Liu, Huibiao [1 ]
Li, Yuliang [1 ]
机构：
[1] Chinese Acad Sci, BNLMS, Inst Chem, Key Lab Organ Solids, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2008年 / 46卷 / 22期
关键词：
BODIPY; conjugated polymers; NLO; UV-vis spectroscopy;
D O I：
10.1002/pola.23045
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of novel conjugated poly(aryleneethynylene)s (PAEs) co-containing BODIPY have been synthesized and characterized, and their third-order nonlinear optical properties were studied using the Z-scan technique. Interestingly, by introducing the BODIPY skeleton into the PAE backbone, the polymers showed that their nonlinear optical properties were dependent on the BODIPY component. From poly-4 to poly-1, the third-order nonlinear optical properties of the polymers enhanced regularly with the increase of the BODIPY component of the copolymers, indicating that the BODIPY component played decisive roles in enhancing the nonlinear optical properties. (C) 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 7401-7410,2008
引用
收藏
页码：7401 / 7410
页数：10
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