[Me3Si(CF3)F]- and [Me3Si(CF3)2]-:: Reactive intermediates in fluoride-initiated trifluoromethylation with Me3SiCF3 -: An NMR study

被引：0

作者：

Maggiarosa, N

Tyrra, W

Naumann, D

Kirij, NV

Yagupolskii, YL

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-253660 Kiev 94, Ukraine

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 15期

关键词：

fluorine; intermediates; NMR spectroscopy; silicon trifluoromethylations;

D O I：

10.1002/(SICI)1521-3773(19990802)38:15<2252::AID-ANIE2252>3.0.CO;2-Z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The long-postulated reactive intermediates of polar fluoride-initiated trifluoromethylations with Me3SiCF3 (see scheme) were identified by NMR spectroscopy as [Me3Si(CF3)F]- and [Me3Si(CF3)2]-.

引用

页码：2252 / 2253

页数：2

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