[Me3Si(CF3)F]- and [Me3Si(CF3)2]-:: Reactive intermediates in fluoride-initiated trifluoromethylation with Me3SiCF3 -: An NMR study

被引：0
|
作者：
Maggiarosa, N
Tyrra, W
Naumann, D
Kirij, NV
Yagupolskii, YL
机构：
[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany
[2] Natl Acad Sci Ukraine, Inst Organ Chem, UA-253660 Kiev 94, Ukraine
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 15期
关键词：
fluorine; intermediates; NMR spectroscopy; silicon trifluoromethylations;
D O I：
10.1002/(SICI)1521-3773(19990802)38:15<2252::AID-ANIE2252>3.0.CO;2-Z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The long-postulated reactive intermediates of polar fluoride-initiated trifluoromethylations with Me3SiCF3 (see scheme) were identified by NMR spectroscopy as [Me3Si(CF3)F]- and [Me3Si(CF3)2]-.
引用
收藏
页码：2252 / 2253
页数：2
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